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The kinetic theory of gases deals not only with gases in thermodynamic equilibrium, but also very importantly with gases not in thermodynamic equilibrium. This means using Kinetic Theory to consider what are known as "transport properties", such as viscosity, thermal conductivity, mass diffusivity and thermal diffusion.
The kinetic theory of gases applies to the classical ideal gas, which is an idealization of real gases. In real gases, there are various effects (e.g., van der Waals interactions , vortical flow, relativistic speed limits, and quantum exchange interactions ) that can make their speed distribution different from the Maxwell–Boltzmann form.
The (Newtonian) kinetic energy of a particle of mass m, velocity v is given by = | | = (+ +), where v x, v y and v z are the Cartesian components of the velocity v.Here, H is short for Hamiltonian, and used henceforth as a symbol for energy because the Hamiltonian formalism plays a central role in the most general form of the equipartition theorem.
This article inspired further work based on the twin ideas that substances are composed of indivisible particles, and that heat is a consequence of the particle motion; movement that evolves in accordance with Newton's laws. The work, known as the kinetic theory of gases, was done principally by Clausius, James Clerk Maxwell, and Ludwig Boltzmann.
The two-dimensional point vortex gas is a discrete particle model used to ... The Hamiltonian H is the interaction term of the fluid's integrated kinetic energy; it ...
According to the assumptions of the kinetic theory of ideal gases, one can consider that there are no intermolecular attractions between the molecules, or atoms, of an ideal gas. In other words, its potential energy is zero. Hence, all the energy possessed by the gas is the kinetic energy of the molecules, or atoms, of the gas.
In other words, the configuration of particle A in state 1 and particle B in state 2 is different from the case in which particle B is in state 1 and particle A is in state 2. This assumption leads to the proper (Boltzmann) statistics of particles in the energy states, but yields non-physical results for the entropy, as embodied in the Gibbs ...
Independent-particle models in nuclear physics require the undisturbed orbiting of nucleons within the nucleus before they interact with other nucleons. [12] The effective mean free path of a nucleon in nuclear matter must be somewhat larger than the nuclear dimensions in order to allow the use of the independent particle model.
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