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An alloy is a mixture of chemical elements of which in most cases at least one is a metallic element, ... Examples of substitutional alloys include bronze and brass ...
Fundamentally, the Hume-Rothery rules are restricted to binary systems that form either substitutional or interstitial solid solutions. However, this approach limits assessing advanced alloys which are commonly multicomponent systems. Free energy diagrams (or phase diagrams) offer in-depth knowledge of equilibrium restraints in complex systems.
Substitutional solid solution strengthening occurs when the solute atom is large enough that it can replace solvent atoms in their lattice positions. Some alloying elements are only soluble in small amounts, whereas some solvent and solute pairs form a solution over the whole range of binary compositions.
The propensity for any two substances to form a solid solution is a complicated matter involving the chemical, crystallographic, and quantum properties of the substances in question. Substitutional solid solutions, in accordance with the Hume-Rothery rules, may form if the solute and solvent have: Similar atomic radii (15% or less difference)
Islamic Golden Age brass astrolabe Brass lectern with an eagle. Attributed to Aert van Tricht, Limburg (Netherlands), c. 1500.. Brass is an alloy of copper and zinc, in proportions which can be varied to achieve different colours and mechanical, electrical, acoustic and chemical properties, [1] but copper typically has the larger proportion, generally 2 ⁄ 3 copper and 1 ⁄ 3 zinc.
Pewter (/ ˈ p juː t ər /) is a malleable metal alloy consisting of tin (85–99%), antimony (approximately 5–10%), copper (2%), bismuth, and sometimes silver. [1] In the past, it was an alloy of tin and lead , but most modern pewter, in order to prevent lead poisoning , is not made with lead.
In some cases where the radius of the substitutional atom (ion) is substantially smaller than that of the atom (ion) it is replacing, its equilibrium position can be shifted away from the lattice site. These types of substitutional defects are often referred to as off-center ions. There are two different types of substitutional defects ...
Aluminium–scandium alloys (AlSc) are aluminum alloys that consist largely of aluminium (Al) and traces of scandium (Sc) as the main alloying elements.In principle, aluminium alloys strengthened with additions of scandium are very similar to traditional nickel-base superalloys in that both are strengthened by coherent, coarsening resistant precipitates with an ordered L1 2 structure.