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The lanthanide contraction is the greater-than-expected decrease in atomic radii and ionic radii of the elements in the lanthanide series, from left to right. It is caused by the poor shielding effect of nuclear charge by the 4f electrons along with the expected periodic trend of increasing electronegativity and nuclear charge on moving from left to right.
The lanthanide contraction, i.e. the reduction in size of the Ln 3+ ion from La 3+ (103 pm) to Lu 3+ (86.1 pm), is often explained by the poor shielding of the 5s and 5p electrons by the 4f electrons.
A metal ion in aqueous solution or aqua ion is a cation, dissolved in water, of chemical formula [M(H 2 O) n] z+.The solvation number, n, determined by a variety of experimental methods is 4 for Li + and Be 2+ and 6 for most elements in periods 3 and 4 of the periodic table.
Group 3 is the first group of transition metals in the periodic table. This group is closely related to the rare-earth elements. It contains the four elements scandium (Sc), yttrium (Y), lutetium (Lu), and lawrencium (Lr). The group is also called the scandium group or scandium family after its lightest member.
For all actinides, oxides AnO 3 are amphoteric and An 2 O 3, AnO 2 and An 2 O 5 are basic, they easily react with water, forming bases: [93] An 2 O 3 + 3 H 2 O → 2 An(OH) 3 . These bases are poorly soluble in water and by their activity are close to the hydroxides of rare-earth metals. [ 93 ]
Cisplatin, PtCl 2 (NH 3) 2, is a coordination complex of platinum(II) with two chloride and two ammonia ligands.It is one of the most successful anticancer drugs. A coordination complex is a chemical compound consisting of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands ...
The Na + /K +-ATPase, as well as effects of diffusion of the involved ions, are major mechanisms to maintain the resting potential across the membranes of animal cells.. The relatively static membrane potential of quiescent cells is called the resting membrane potential (or resting voltage), as opposed to the specific dynamic electrochemical phenomena called action potential and graded ...
The number of ways to link an X to two external lines is 4 × 3, and either X could link up to either pair, giving an additional factor of 2. The remaining two half-lines in the two X s can be linked to each other in two ways, so that the total number of ways to form the diagram is 4 × 3 × 4 × 3 × 2 × 2, while the denominator is 4! × 4 ...