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Toluene (/ ˈ t ɒ l. j u iː n /), also known as toluol (/ ˈ t ɒ l. j u. ɒ l , - ɔː l , - oʊ l / ), is a substituted aromatic hydrocarbon [ 15 ] with the chemical formula C 6 H 5 CH 3 , often abbreviated as PhCH 3 , where Ph stands for the phenyl group.
Ethyltoluene is produced by ethylation of toluene: CH 3 C 6 H 5 + C 2 H 4 → CH 3 C 6 H 4 C 2 H 5. Over typical acid catalysts, this process gives a mixture of the 2-, 3-, and 4- isomers. Using a modified zeolite catalyst, the alkylation is shape-selective for the 4- isomer. [1] 4-Ethyltoluene is subjected dehydrogenation to give 4 ...
Industrially, the diazonium method is reserved for 3-chlorotoluene. The industrial route to 2- and 4-chlorotoluene entails direct reaction of toluene with chlorine. The more valuable 4-chlorotoluene is separated from 2-chlorotoluene by distillation. Distillation cannot be applied to separating 3-chlorotoluene from 4-chlorotoluene. [2]
Toluene derivatives (3 P) 2-Tolyl compounds (18 P) 3-Tolyl compounds (10 P) 4-Tolyl compounds (1 C, 25 P) Pages in category "Toluenes" The following 15 pages are in ...
In 1841, Henri Étienne Sainte-Claire Deville isolated toluene by the dry distillation of tolu balsam. [4] The resin is used in traditional medicine by the people of Central America and South America. [5] It got its name because it was shipped to Europe from Tolú, Colombia. [2]
Toluene (or methylbenzene) is a common chemical found in chemistry laboratories. An alkylbenzene is a chemical compound that contains a monocyclic aromatic ring attaching to one or more saturated hydrocarbon chains. [1] Alkylbenzenes are derivatives of benzene, in which one or more hydrogen atoms are replaced by alkyl groups.
A laboratory route to o- and p-iodotoluene proceeds from toluene, which is treated with a mixture of iodine and nitric acid in an electrophilic aromatic substitution.The resulting mixture of o and p-iodotoluene is then separated by fractional freezing; cooling the mixture in an ice bath results in solidification of p-iodotoluene, which can then be isolated by filtration, while the o ...
In addition to p-cymene, two less common geometric isomers are o-cymene, in which the alkyl groups are ortho-substituted, and m-cymene, in which they are meta-substituted.