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In the simplest example oxygen can be used as it exists naturally in its triplet state (i.e. it is a diradical). This is referred to as air inhibition and is a diffusion-controlled reaction with rates typically in the order of 10 7 –10 9 mol −1 s −1 , [ 3 ] the resulting peroxy radicals (ROO•) are less reactive towards polymerisation.
Lean air is a gas mixture with an oxygen content lower than 20.95% (the oxygen content of the normal breathing air).Lean air is made from a gas mixture of air with nitrogen or of pure oxygen with nitrogen and is used in several production processes where a product covering with pure nitrogen can be dangerous, undesirable or more expensive.
Acrylic acid and its esters readily combine with themselves (to form polyacrylic acid) or other monomers (e.g. acrylamides, acrylonitrile, vinyl compounds, styrene, and butadiene) by reacting at their double bond, forming homopolymers or copolymers, which are used in the manufacture of various plastics, coatings, adhesives, elastomers, as well ...
Photo-oxidation is a form of photodegradation and begins with formation of free radicals on the polymer chain, which then react with oxygen in chain reactions. For many polymers the general autoxidation mechanism is a reasonable approximation of the underlying chemistry.
An α,β-unsaturated acid is a type of α,β-unsaturated carbonyl compound that consists of an alkene conjugated to a carboxylic acid. [3] The simplest example is acrylic acid (CH 2 =CHCO 2 H). These compounds are prone to polymerization, giving rise to the large area of polyacrylate plastics. Acrylate polymers are derived from but do not ...
Catalytic oxidation are processes that rely on catalysts to introduce oxygen into organic and inorganic compounds. Many applications, including the focus of this article, involve oxidation by oxygen. Such processes are conducted on a large scale for the remediation of pollutants, production of valuable chemicals, and the production of energy. [1]
In rodent models, butyl acrylate is metabolized by carboxylesterase or reactions with glutathione; this detoxification produces acrylic acid, butanol, and mercapturic acid waste, which are excreted. [5] [6] [7] Exposure can occur through inhalation, skin and/or eye contact absorption, and ingestion. [8]
Acrylates (IUPAC: prop-2-enoates) are the salts, esters, and conjugate bases of acrylic acid. The acrylate ion is the anion CH 2 =CHCO − 2. Often, acrylate refers to esters of acrylic acid, the most common member being methyl acrylate. These acrylates contain vinyl groups.