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Sodium thiosulfate (sodium thiosulphate) is an inorganic compound with the formula Na 2 S 2 O 3 ·(H 2 O) x. Typically it is available as the white or colorless pentahydrate (x = 5), which is a white solid that dissolves well in water. The compound is a reducing agent and a ligand, and these properties underpin its applications. [2]
Fixation is commonly achieved by treating the film or paper with a solution of thiosulfate salt. Popular salts are sodium thiosulfate—commonly called hypo—and ammonium thiosulfate—commonly used in modern rapid fixer formulae. [1] Fixation by thiosulfate involves these chemical reactions (X = halide, typically Br −): [2]
Thiosulfate (IUPAC-recommended spelling; sometimes thiosulphate in British English) is an oxyanion of sulfur with the chemical formula S 2 O 2− 3.Thiosulfate also refers to the compounds containing this anion, which are the salts of thiosulfuric acid, such as sodium thiosulfate Na 2 S 2 O 3 and ammonium thiosulfate (NH 4) 2 S 2 O 3.
Sodium thiosulfate is a classical antidote to cyanide poisoning, [10] For this purpose it is used after the medication sodium nitrite and typically only recommended for severe cases. [4] [6] It is given by injection into a vein. [4] In this use, sodium nitrite creates methemoglobinemia which removes cyanide from mitochondria. [6]
Chlorine releasing solutions, such as liquid bleach and solutions of bleaching powder, can burn the skin and cause eye damage, [2] especially when used in concentrated forms. As recognized by the NFPA, however, only solutions containing more than 40% sodium hypochlorite by weight are considered hazardous oxidizers.
Anhydrous lithium hypochlorite is stable at room temperature; however, sodium hypochlorite is explosive as an anhydrous solid. [6] The pentahydrate (NaOCl·(H 2 O) 5) is unstable above 0 °C; [7] although the more dilute solutions encountered as household bleach are more stable. Potassium hypochlorite (KOCl) is known only in solution.
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