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The self-ionization of water (also autoionization of water, autoprotolysis of water, autodissociation of water, or simply dissociation of water) is an ionization reaction in pure water or in an aqueous solution, in which a water molecule, H 2 O, deprotonates (loses the nucleus of one of its hydrogen atoms) to become a hydroxide ion, OH −.
For example, in the reaction between hydrochloric acid and sodium hydroxide the sodium and chloride ions, Na + and Cl − take no part in the reaction. The reaction is consistent with the Brønsted–Lowry definition because in reality the hydrogen ion exists as the hydronium ion, so that the neutralization reaction may be written as
The hydroxide ion is naturally produced from water by the self-ionization reaction: [2] H 3 O + + OH − ⇌ 2H 2 O. The equilibrium constant for this reaction, defined as K w = [H +][OH −] [note 1] has a value close to 10 −14 at 25 °C, so the concentration of hydroxide ions in pure water is close to 10 −7 mol∙dm −3, to satisfy the ...
The hydrogen ion, or hydronium ion, is a Brønsted–Lowry acid when dissolved in H 2 O and the hydroxide ion is a base because of the autoionization of water reaction + + + An analogous reaction occurs in liquid ammonia
Alkaline hydrolysis usually refers to types of nucleophilic substitution reactions in which the attacking nucleophile is a hydroxide ion. The best known type is saponification: cleaving esters into carboxylate salts and alcohols. In ester hydrolysis, the hydroxide ion nucleophile attacks the carbonyl carbon.
Most notably hydroxyl radicals are produced from the decomposition of hydroperoxides (ROOH) or, in atmospheric chemistry, by the reaction of excited atomic oxygen with water. It is also an important radical formed in radiation chemistry, since it leads to the formation of hydrogen peroxide and oxygen , which can enhance corrosion and stress ...
Hydrogen oxide; Hydrogen hydroxide (H 2 O or HOH) Hydroxylic acid; Dihydrogen monoxide ... Note that the rusting of iron is a reaction between iron and oxygen [95] ...
1. Hydrogen 2. Electron flow 3. Load 4. Oxygen 5. Cathode 6. Electrolyte 7. Anode 8. Water 9. Hydroxide Ions. The alkaline fuel cell (AFC), also known as the Bacon fuel cell after its British inventor, Francis Thomas Bacon, is one of the most developed fuel cell technologies. Alkaline fuel cells consume hydrogen and pure oxygen, to produce ...