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Together with its conjugate base superoxide, hydroperoxyl is an important reactive oxygen species.Unlike • O − 2, which has reducing properties, HO • 2 can act as an oxidant in a number of biologically important reactions, such as the abstraction of hydrogen atoms from tocopherol and polyunstaturated fatty acids in the lipid bilayer.
Acetic anhydride, or ethanoic anhydride, is the chemical compound with the formula (CH 3 CO) 2 O. Commonly abbreviated Ac 2 O, it is the simplest isolable anhydride of a carboxylic acid and is widely used as a reagent in organic synthesis. It is a colorless liquid that smells strongly of acetic acid, which is formed by its reaction with ...
The reaction mechanism involves a two-stage radical process: electrochemical decarboxylation gives a radical intermediate, which combine to form a covalent bond. [2] As an example, electrolysis of acetic acid yields ethane and carbon dioxide: CH 3 COOH → CH 3 COO − → CH 3 COO· → CH 3 · + CO 2 2CH 3 · → CH 3 CH 3
Industrially, it is prepared by carboalkoxylation, i.e., the reaction of ethylene with carbon monoxide and methanol in the presence of a catalyst: C 2 H 4 + CO + MeOH → MeO 2 CCH 2 CH 3 The reaction is catalyzed by nickel carbonyl and palladium(0) complexes.
Important compounds made in this way include tert-butyl hydroperoxide, cumene hydroperoxide and ethylbenzene hydroperoxide: [7] R−H + O 2 → R−OOH. Auto-oxidation reaction is also observed with common ethers, such as diethyl ether, diisopropyl ether, tetrahydrofuran, and 1,4-dioxane. An illustrative product is diethyl ether peroxide.
The first reaction with many volatile organic compounds (VOCs) is the removal of a hydrogen atom, forming water and an alkyl radical (R •): • HO + RH → H 2 O + R • The alkyl radical will typically react rapidly with oxygen forming a peroxy radical: R • + O 2 → RO 2
This reaction requires no base. Under atmospheric conditions the dibromo complex is easily hydrolyzed (1 hr), whereas the dichloro and difluoro complexes are not easily hydrolyzed (1-3 days). The complex TiCl 2 (acac) 2 is fluxional in solution, the NMR spectrum exhibiting a single methyl resonance at room temperature.
In organic chemistry, a ketene is an organic compound of the form RR'C=C=O, where R and R' are two arbitrary monovalent chemical groups (or two separate substitution sites in the same molecule). [1] The name may also refer to the specific compound ethenone H 2 C=C=O, the simplest ketene. [2] Although they are highly useful, most ketenes are ...