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  2. Bond energy - Wikipedia

    en.wikipedia.org/wiki/Bond_energy

    In chemistry, bond energy (BE) is one measure of the strength of a chemical bond. It is sometimes called the mean bond , bond enthalpy , average bond enthalpy , or bond strength . [ 1 ] [ 2 ] [ 3 ] IUPAC defines bond energy as the average value of the gas-phase bond-dissociation energy (usually at a temperature of 298.15 K) for all bonds of the ...

  3. Bond cleavage - Wikipedia

    en.wikipedia.org/wiki/Bond_cleavage

    The triplet and singlet excitation energies of a sigma bond can be used to determine if a bond will follow the homolytic or heterolytic pathway. [2] A metal−metal sigma bond is an exception because the bond's excitation energy is extremely high, thus cannot be used for observation purposes. [2] In some cases, bond cleavage requires catalysts.

  4. Trouton's rule - Wikipedia

    en.wikipedia.org/wiki/Trouton's_rule

    The characteristic of those liquids to which Trouton’s rule cannot be applied is their special interaction between molecules, such as hydrogen bonding. The entropy of vaporization of water and ethanol shows positive deviance from the rule; this is because the hydrogen bonding in the liquid phase lessens the entropy of the phase.

  5. Standard enthalpy of reaction - Wikipedia

    en.wikipedia.org/wiki/Standard_enthalpy_of_reaction

    Standard enthalpy of hydrogenation is defined as the enthalpy change observed when one mole of an unsaturated compound reacts with an excess of hydrogen to become fully saturated. The hydrogenation of one mole of acetylene yields ethane as a product and is described by the equation C 2 H 2 (g) + 2 H 2 (g) → C 2 H 6 (g).

  6. Bond-dissociation energy - Wikipedia

    en.wikipedia.org/wiki/Bond-dissociation_energy

    The term bond-dissociation energy is similar to the related notion of bond-dissociation enthalpy (or bond enthalpy), which is sometimes used interchangeably.However, some authors make the distinction that the bond-dissociation energy (D 0) refers to the enthalpy change at 0 K, while the term bond-dissociation enthalpy is used for the enthalpy change at 298 K (unambiguously denoted DH° 298).

  7. Van 't Hoff equation - Wikipedia

    en.wikipedia.org/wiki/Van_'t_Hoff_equation

    This analysis showed that enthalpically, the water preferred to hydrogen bond to the C-terminus, but entropically it was more favorable to hydrogen bond with the N-terminus. Specifically, they found that C-terminus hydrogen bonding was favored by 4.2–6.4 kJ/mol. The N-terminus hydrogen bonding was favored by 31–43 J/(K mol).

  8. 10 Overrated Foods People Are Pretending to Enjoy - AOL

    www.aol.com/10-overrated-foods-people-pretending...

    3. Foie Gras. Foie gras is probably the ultimate starter-pack item for acting like a rich person, and the one food item that chefs love to cook to appeal to said rich people.Redditors on the other ...

  9. Benson group increment theory - Wikipedia

    en.wikipedia.org/wiki/Benson_group_increment_theory

    The final calculation comes from the CH 3 groups connected to the 2' carbon; C−(C)(H) 3. The total calculations add to −5.15 kcal/mol (−21.6 kJ/mol), which is identical to the experimental value, which can be found in the National Institute of Standards and Technology Chemistry WebBook. [15]

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