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Piper diagram of water samples from the Mtshabezi River, Zimbabwe. Data source: [2] A Piper diagram is a graphical representation of the chemistry of a water sample or samples. The cations and anions are shown by separate ternary plots. The apexes of the cation plot are calcium, magnesium and sodium plus potassium cations.
In groundwater, this oxic-anoxic environment is referred to as the capillary fringe, where the water table meets soil and fills empty pores. Because this transition zone is both oxic and anoxic, electron acceptors and donors are in high abundance and there is a high level of microbial activity, leading to the highest rates of contaminant ...
A ternary flammability diagram, showing which mixtures of methane, oxygen gas, and inert nitrogen gas will burn. A ternary plot, ternary graph, triangle plot, simplex plot, or Gibbs triangle is a barycentric plot on three variables which sum to a constant. [1] It graphically depicts the ratios of the three variables as positions in an ...
The GWB is an integrated geochemical modeling package used for balancing chemical reactions, calculating stability diagrams and the equilibrium states of natural waters, tracing reaction processes, modeling reactive transport, plotting the results of these calculations, and storing the related data.
Geochemical modeling is used in a variety of fields, including environmental protection and remediation, [1] the petroleum industry, and economic geology. [2] Models can be constructed, for example, to understand the composition of natural waters; the mobility and breakdown of contaminants in flowing groundwater or surface water; the ion speciation of plant nutrients in soil and of regulated ...
A miscibility gap between isostructural phases may be described as the solvus, a term also used to describe the boundary on a phase diagram between a miscibility gap and other phases. [2] Thermodynamically, miscibility gaps indicate a maximum (e.g. of Gibbs energy) in the composition range. [3] [4]
The groundwater flow between neighboring prisms is calculated using 2-dimensional horizontal groundwater flow equations. Vertical flows are found by applying one-dimensional flow equations in a vertical sense, or they can be derived from the water balance: excess of horizontal inflow over horizontal outflow (or vice versa) is translated into ...
In physical organic chemistry, a free-energy relationship or Gibbs energy relation relates the logarithm of a reaction rate constant or equilibrium constant for one series of chemical reactions with the logarithm of the rate or equilibrium constant for a related series of reactions. [1]