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A deoxyadenosyl radical is a free radical that is structurally related to adenosine by removal of a 5′-hydroxy group from adenosine. This radical occurs in nature as a reactive intermediate. This radical occurs in nature as a reactive intermediate.
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5′-Phosphoribosyl-5-aminoimidazole (or aminoimidazole ribotide, AIR) is a biochemical intermediate in the formation of purine nucleotides via inosine-5-monophosphate, and hence is a building block for DNA and RNA. [1] The vitamins thiamine [2] [3] and cobalamin [4] also contain fragments derived from AIR. [5]
5-Ethynyl-2′-deoxyuridine (EdU) is a thymidine analogue which is incorporated into the DNA of dividing cells. EdU is used to assay DNA synthesis in cell culture and detect cells in embryonic, neonatal and adult animals which have undergone DNA synthesis. [ 1 ]
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The proposed biosynthesis of 5-deoxyinositol begins with the conversion of D-glucose to myo-inositol. [4] In this pathway, D -glucose is phosphorylated to form D -glucose-6-phosphate . The NAD+ dependent enzyme inositol 1-phosphate synthase (I1PS) then catalyzes the subsequent oxidation, enolization, aldol cyclization, and reduction of D ...