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Anti-periplanar geometry will put a bonding orbital and an anti-bonding orbital approximately parallel to each other, or syn-periplanar. Figure 6 is another representation of 2-chloro-2,3-dimethylbutane (Figure 5), showing the C–H bonding orbital, σ C–H, and the C–Cl anti-bonding orbital, σ* C–Cl, syn-periplanar.
The concepts of syn and anti addition are used to characterize the different reactions of organic chemistry by reflecting the stereochemistry of the products in a reaction. The type of addition that occurs depends on multiple different factors of a reaction, and is defined by the final orientation of the substituents on the parent molecule .
Practice theory (or praxeology, theory of social practices) is a body of social theory within anthropology and sociology that explains society and culture as the result of structure and individual agency. Practice theory emerged in the late 20th century and was first outlined in the work of the French sociologist Pierre Bourdieu.
The analytic–synthetic distinction is a semantic distinction used primarily in philosophy to distinguish between propositions (in particular, statements that are affirmative subject–predicate judgments) that are of two types: analytic propositions and synthetic propositions. Analytic propositions are true or not true solely by virtue of ...
The disposition of the formed stereocenters is deemed syn or anti, depending if they are on the same or opposite sides of the main chain: Syn and anti products from an aldol (addition) reaction. The principal factor determining an aldol reaction's stereoselectivity is the enolizing metal counterion.
Relative conformation energy diagram of butane as a function of dihedral angle. [9] A: antiperiplanar, anti or trans. B: synclinal or gauche. C: anticlinal or eclipsed. D: synperiplanar or cis. [2] Rotating their carbon–carbon bonds, the molecules ethane and propane have three local energy minima.
Aspects of the Theory of Syntax (known in linguistic circles simply as Aspects [1]) is a book on linguistics written by American linguist Noam Chomsky, first published in 1965. In Aspects , Chomsky presented a deeper, more extensive reformulation of transformational generative grammar (TGG), a new kind of syntactic theory that he had introduced ...
The constituent is defined in a theory-neutral manner: Constituent A given word/node plus all the words/nodes that that word/node dominates. This definition is neutral with respect to the dependency vs. constituency distinction. It allows one to compare the ICA across the two types of structure.