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Thermal conduction is the diffusion of thermal energy (heat) within one material or between materials in contact. The higher temperature object has molecules with more kinetic energy; collisions between molecules distributes this kinetic energy until an object has the same kinetic energy throughout.
In a simplified picture of a solid, thermal conduction occurs by two mechanisms: 1) the migration of free electrons and 2) lattice vibrations . The first mechanism dominates in pure metals and the second in non-metallic solids. In liquids, by contrast, the precise microscopic mechanisms of thermal conduction are poorly understood. [32]
The electrons are bumped to the conduction energy band by thermal energy, where they flow freely, and in doing so leave behind holes in the valence band, which also flow freely. The electric resistance of a typical intrinsic (non doped) semiconductor decreases exponentially with temperature following an Arrhenius model:
These are called non-ohmic or non-linear, and their current–voltage curves are not straight lines through the origin. Resistance and conductance can still be defined for non-ohmic elements. However, unlike ohmic resistance, non-linear resistance is not constant but varies with the voltage or current through the device; i.e., its operating point.
Mixtures may have variable thermal conductivities due to composition. Note that for gases in usual conditions, heat transfer by advection (caused by convection or turbulence for instance) is the dominant mechanism compared to conduction. This table shows thermal conductivity in SI units of watts per metre-kelvin (W·m −1 ·K −1).
The most common examples are non-metals. A perfect insulator does not exist because even insulators contain small numbers of mobile charges (charge carriers) which can carry current. In addition, all insulators become electrically conductive when a sufficiently large voltage is applied that the electric field tears electrons away from the atoms.
An example of steady state conduction is the heat flow through walls of a warm house on a cold day—inside the house is maintained at a high temperature and, outside, the temperature stays low, so the transfer of heat per unit time stays near a constant rate determined by the insulation in the wall and the spatial distribution of temperature ...
Essentially what is occurring is a long chain of momentum transfer between mobile charge carriers; the Drude model of conduction describes this process more rigorously. This momentum transfer model makes metal an ideal choice for a conductor; metals, characteristically, possess a delocalized sea of electrons which gives the electrons enough ...