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  2. N-Bromosuccinimide - Wikipedia

    en.wikipedia.org/wiki/N-Bromosuccinimide

    NBS will react with alkenes 1 in aqueous solvents to give bromohydrins 2. The preferred conditions are the portionwise addition of NBS to a solution of the alkene in 50% aqueous DMSO, DME, THF, or tert-butanol at 0 °C. [3] Formation of a bromonium ion and immediate attack by water gives strong Markovnikov addition and anti stereochemical ...

  3. Wohl–Ziegler bromination - Wikipedia

    en.wikipedia.org/wiki/Wohl–Ziegler_bromination

    The generation of NBS radicals depicted in the Bloomfield mechanism has been shown to be far more difficult than imagined when it was proposed, which is why it has failed as a proper model throughout the years; however, evidence suggests that the Bloomfield mechanism is still acceptable for the oxidation of alcohols using NBS. [10] In the ...

  4. Ramberg–Bäcklund reaction - Wikipedia

    en.wikipedia.org/wiki/Ramberg–Bäcklund_reaction

    The necessary α-halo sulfones are accessible through oxidation of the corresponding α-halo sulfides with peracids such as meta-chloroperbenzoic acid; oxidation of sulfides takes place selectively in the presence of alkenes and alcohols. α-Halo sulfides may in turn be synthesized through the treatment of sulfides with halogen electrophiles such as N-chlorosuccinimide or N-bromosuccinimide.

  5. Grieco elimination - Wikipedia

    en.wikipedia.org/wiki/Grieco_elimination

    The Grieco elimination is an organic reaction describing the elimination reaction of an aliphatic primary alcohol through a selenide to a terminal alkene. [1] [2] It is named for Paul Grieco. The alcohol first reacts with o-nitrophenylselenocyanate and tributylphosphine to form a selenide via a nucleophilic substitution on the electron ...

  6. Grob fragmentation - Wikipedia

    en.wikipedia.org/wiki/Grob_fragmentation

    [8] [9] The reaction products are an electrofugal fragment, an imine, and a nucleofugal fragment (such as an alcohol). 3-Aza-Grob Fragmentation Scheme. 3-aza-Grob fragmentation can proceed with several different nucleofuges. The reaction mechanism has been reported to begin with the reduction of an ether protected amide to form a secondary ...

  7. Schenck ene reaction - Wikipedia

    en.wikipedia.org/wiki/Schenck_ene_reaction

    The Schenck ene reaction or the Schenk reaction is the reaction of singlet oxygen with alkenes to yield hydroperoxides. The hydroperoxides can be reduced to allylic alcohols or eliminate to form unsaturated carbonyl compounds. It is a type II photooxygenation reaction, and is discovered in 1944 by Günther Otto Schenck. [1]

  8. Ei mechanism - Wikipedia

    en.wikipedia.org/wiki/Ei_mechanism

    In organic chemistry, the E i mechanism (Elimination Internal/Intramolecular), also known as a thermal syn elimination or a pericyclic syn elimination, is a special type of elimination reaction in which two vicinal (adjacent) substituents on an alkane framework leave simultaneously via a cyclic transition state to form an alkene in a syn elimination. [1]

  9. Hydroboration - Wikipedia

    en.wikipedia.org/wiki/Hydroboration

    This chemical reaction is useful in the organic synthesis of organic compounds. [1] Hydroboration produces organoborane compounds that react with a variety of reagents to produce useful compounds, such as alcohols, amines, or alkyl halides. The most widely known reaction of the organoboranes is oxidation to produce alcohols from alkenes.