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The addition can be promoted with base [1] (Favorskii reaction) or with Lewis acid catalysts. [2] 2-Methylbut-3-yn-2-ol is produced on an industrial scale as a precursor to terpenes and terpenoids. 2-Methylbut-3-yn-2-ol is an intermediate in this industrial route to geraniol. [3] 2-Methylbut-3-yn-2-ol also is used as a monoprotected version of ...
[1] Synthesis of an ynone. An alternative is the direct coupling of an acyl chloride with a terminal alkyne, using a copper-based nanocatalyst: [2] Synthesis of an ynone. Other methods utilize an oxidative cleavage of an aldehyde, followed by reaction with a hypervalent alkynyl iodide, using a gold catalyst. [3]
Isoprenol, also known as 3-methylbut-3-en-1-ol, is a hemiterpene alcohol. It is produced industrially as an intermediate to 3-methylbut-2-en-1-ol (prenol): global production in 2001 can be estimated as 6–13 thousand tons.
The structure of a conjugated enyne. An enyne is an organic compound containing a C=C double bond and a C≡C triple bond . [1] It is called a conjugated enyne when the double and triple bonds are conjugated. The term is a contraction of the terms alkene and alkyne. The simplest enyne is vinylacetylene. [2]
Another method of production involves the isomerization of 3-methylbut-3-en-1-ol using CuO–ZnO as a catalyst. A mixture of 3-methylbut-3-en-1-ol and 3-methylbut-2-en-1-ol may also be used. These starting materials are obtained from a reaction between isobutene and formaldehyde: [3] CH 3 CH 3 CCH 2 + CH 2 O → (CH 3) 2 CHCH 2 CHO
2-Butyne (dimethylacetylene, crotonylene or but-2-yne) is an alkyne with chemical formula CH 3 C≡CCH 3. Produced artificially, it is a colorless, volatile, pungent liquid at standard temperature and pressure .
The branched isomers are 2-methylbut-1-ene, 3-methylbut-1-ene (isopentene), and 2-methylbut-2-ene (isoamylene). Isoamylene is one of the three main byproducts of deep catalytic cracking (DCC), which is very similar to the operation of fluid catalytic cracking (FCC).
Prenol, or 3-methyl-2-buten-1-ol, is a natural alcohol. It is one of the most simple terpenoids . It is a clear colorless oil that is reasonably soluble in water and miscible with most common organic solvents.