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Sulfates in solution in contact with concrete can cause chemical changes to the cement, which can cause significant microstructural effects leading to the weakening of the cement binder (chemical sulfate attack). Sulfate solutions can also cause damage to porous cementitious materials through crystallization and recrystallization (salt attack). [7]
Pyrite is the most common of sulfide minerals and is widespread in igneous, metamorphic, and sedimentary rocks. It is a common accessory mineral in igneous rocks, where it also occasionally occurs as larger masses arising from an immiscible sulfide phase in the original magma.
When it reacts with concrete, it causes the slab to expand, lifting, distorting and cracking as well as exerting a pressure onto the surrounding walls which can cause movements significantly weakening the structure. Some infill materials frequently encountered in building fondations and causing sulfate attack are the following: [2] Red Ash
Also, the mineral pyrite is both the most common and most abundant sulfide mineral in the Earth's crust. [6] If rocks containing pyrite undergo metamorphism, there is a gradual release of volatile components like water and sulfur from pyrite. [6] The loss of sulfur causes pyrite to recrystallize into pyrrhotite. [6]
a description of the standard analytical techniques used to quantify these hazards (e.g., Acid Base Accounting, Acid Volatile Sulfide analysis, and sequential metal/metalloid extraction). These manuals do not provide guidance on the management of acid sulfate soils. For topic-specific management strategies see:
The hydrogen sulfide gas is biochemically oxidized in the presence of moisture to form sulfuric acid. The effect of sulfuric acid on concrete and steel surfaces exposed to severe wastewater environments can be devastating. [1] In the USA alone, corrosion causes sewer asset losses estimated at $14 billion per year. [2]
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Examples may include sulfate-reducing bacteria (or sulfur-reducing bacteria), which produce sulfide and often cause corrosion of ferrous metals (and other alloys). Sulfide-oxidizing bacteria (e.g., Acidithiobacillus ), on the other hand, can produce sulfuric acid, and can be involved in corrosion of concrete.