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Vanadium(III) oxide is the inorganic compound with the formula V 2 O 3. It is a black solid prepared by reduction of V 2 O 5 with hydrogen or carbon monoxide. [3] [4] It is a basic oxide dissolving in acids to give solutions of vanadium (III) complexes. [4] V 2 O 3 has the corundum structure. [4]
Vanadium(II) oxide is the inorganic compound with the idealized formula VO. It is one of the several binary vanadium oxides. It adopts a distorted NaCl structure and contains weak V−V metal to metal bonds. VO is a semiconductor owing to delocalisation of electrons in the t 2g orbitals.
Phases with the general formula V n O 2n+1 exist between V 2 O 5 and VO 2. Examples of these phases include V 3 O 7, V 4 O 9 and V 6 O 13. [1] Phases with the general formula V n O 2n−1 exist between VO 2 and V 2 O 3. [1] Called Magnéli phases for Arne Magnéli, [2] they are examples of crystallographic shear compounds based on the rutile ...
There are also vanadates, such as rhodium vanadate, RhVO 4, which has a statistical rutile structure where the Rh 3+ and V 5+ ions randomly occupy the Ti 4+ positions in the rutile lattice, [3] that do not contain a lattice of cations and balancing vanadate anions but are mixed oxides. In chemical nomenclature when vanadate forms part of the ...
From left: [V(H 2 O) 6] 2+ (lilac), [V(H 2 O) 6] 3+ (green), [VO(H 2 O) 5] 2+ (blue) and [VO(H 2 O) 5] 3+ (yellow).. Vanadium compounds are compounds formed by the element vanadium (V). The chemistry of vanadium is noteworthy for the accessibility of the four adjacent oxidation states 2–5, whereas the chemistry of the other group 5 elements, niobium and tantalum, are somewhat more limited to ...
These solutions contain mainly the ions HVO 4 2− and V 2 O 7 4− between pH 9 and pH 13, but below pH 9 more exotic species such as V 4 O 12 4− and HV 10 O 28 5− (decavanadate) predominate. Upon treatment with thionyl chloride, it converts to the volatile liquid vanadium oxychloride, VOCl 3: [11] V 2 O 5 + 3 SOCl 2 → 2 VOCl 3 + 3 SO 2
Vanadium(IV) oxide or vanadium dioxide is an inorganic compound with the formula VO 2.It is a dark blue solid. Vanadium(IV) dioxide is amphoteric, dissolving in non-oxidising acids to give the blue vanadyl ion, [VO] 2+ and in alkali to give the brown [V 4 O 9] 2− ion, or at high pH [VO 4] 4−. [4]
Vanadium is a chemical element; it has symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal . The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( passivation ) somewhat stabilizes the free metal against further oxidation .