Search results
Results from the WOW.Com Content Network
Indium acetate is an acetate of indium, with the chemical formula In(CH 3 COO) 3. It is soluble in water, acetic acid and mineral acids. [ 1 ] It is the precursor of indium-containing compounds such as the solar cell materials CuInS 2 [ 2 ] and indium phosphide quantum dots .
Ruthenium(III) acetate, commonly known as basic ruthenium acetate, [1] describes a family of salts where the cation has the formula [Ru 3 O(O 2 CCH 3) 6 (OH 2) 3] +.A representative derivative is the dihydrate of the tetrafluoroborate salt [Ru 3 O(O 2 CCH 3) 6 (OH 2) 3]BF 4 (H 2 O) 2, which is the source of the data in the table above. [2]
3, which can be obtained in anhydrous form from direct oxidation of iridium powder by chlorine at 650 °C, [15] or in hydrated form by dissolving Ir 2 O 3 in hydrochloric acid, is often used as a starting material for the synthesis of other Ir(III) compounds. [2] Another compound used as a starting material is ammonium hexachloroiridate(III ...
Organoiridium compounds share many characteristics with those of rhodium, but less so with cobalt. Iridium can exist in oxidation states of -III to +V, but iridium(I) and iridium(III) are the more common. iridium(I) compounds (d 8 configuration) usually occur with square planar or trigonal bipyramidal geometries, whereas iridium(III) compounds (d 6 configuration) typically have an octahedral ...
Applications include their use as NMR "shift reagents" and as catalysts for organic synthesis, and precursors to industrial hydroformylation catalysts. C 5 H 7 O − 2 in some cases also binds to metals through the central carbon atom; this bonding mode is more common for the third-row transition metals such as platinum(II) and iridium(III).
Indole-3-acetic acid (IAA, 3-IAA) is the most common naturally occurring plant hormone of the auxin class. It is the best known of the auxins, and has been the subject of extensive studies by plant physiologists. [1]
[1]: 293–307 The process is based on an iridium-containing catalyst, such as the complex [Ir(CO) 2 I 2] − (1). The Cativa and Monsanto processes are sufficiently similar that they can use the same chemical plant. Initial studies by Monsanto had shown iridium to be less active than rhodium for the carbonylation of methanol. [2]
A typical example of this category viz. novel hexacoordinated orthometalated rhodium(III) thiolato complex trans-[Rh(C ∧ N ∧ S)Cl(PPh 3) 2] was synthesized from benzyl 2-(phenylazo)phenyl thioether and RhCl 3 ·3H 2 O in the presence of excess PPh 3 via in situ C(sp 2)−H and C(sp 3)−S bond scissions. This is the first example for a ...