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The PUREX process was invented by Herbert H. Anderson and Larned B. Asprey at the Metallurgical Laboratory at the University of Chicago, as part of the Manhattan Project under Glenn T. Seaborg; their patent "Solvent Extraction Process for Plutonium" filed in 1947, [14] mentions tributyl phosphate as the major reactant which accomplishes the ...
PUREX, the current standard method, is an acronym standing for Plutonium and Uranium Recovery by EXtraction. The PUREX process is a liquid-liquid extraction method used to reprocess spent nuclear fuel, to extract uranium and plutonium, independent of each other, from the fission products. This is the most developed and widely used process in ...
It is possible, however, to remove the americium from the plutonium by a chemical separation process. Even under the worst conditions, the americium/plutonium mixture is less radioactive than a spent-fuel dissolution liquor, so it should be relatively straightforward to recover the plutonium by PUREX or another aqueous reprocessing method.
The UREX process is a PUREX process which has been modified to prevent the plutonium being extracted. This can be done by adding a plutonium reductant before the first metal extraction step. In the UREX process, ~99.9% of the uranium and >95% of technetium are separated from each other and the other fission products and actinides. The key is ...
The current method of choice is to use the PUREX liquid–liquid extraction process which uses a tributyl phosphate/hydrocarbon mixture to extract both uranium and plutonium from nitric acid. This extraction is of the nitrate salts and is classed as being of a solvation mechanism. For example, the extraction of plutonium by an extraction agent ...
The most common reprocessing technique, PUREX, presents a particular concern since it was expressly designed to separate plutonium. Early proposals for the breeder-reactor fuel cycle posed an even greater proliferation concern because they would use PUREX to separate plutonium in a highly attractive isotopic form for use in nuclear weapons. [50 ...
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The lifecycle of fuel in the present US system. If put in one place the total inventory of spent nuclear fuel generated by the commercial fleet of power stations in the United States, would stand 7.6 metres (25 ft) tall and be 91 metres (300 ft) on a side, approximately the footprint of one American football field.