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Lithium bromide (LiBr) is a chemical compound of lithium and bromine. Its extreme hygroscopic character makes LiBr useful as a desiccant in certain air conditioning systems. [ 9 ]
Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids. They are soluble in water and slightly soluble in ethanol. Both are available commercially. While classified as a strong base, lithium hydroxide is the weakest known alkali metal hydroxide.
The filtrate consists of fairly pure methyllithium. Alternatively, commercial methyllithium can be treated with dioxane to precipitate LiBr(dioxane), which can be removed by filtration. [2] The use of halide-free vs LiBr-MeLi has a decisive effect on some syntheses. [3]
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The salt theoretically results from the neutralization of hypofluorous acid (HOF) and lithium hydroxide (LiOH). It can be formed by the action of fluorine on lithium hydroxide: 6 F 2 + 6 LiOH → 2 LiF + O 2 + 4 LiOF + 6 HF
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