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The alkali–silica reaction (ASR), also commonly known as concrete cancer, [3] is a deleterious internal swelling reaction that occurs over time in concrete between the highly alkaline cement paste and the reactive amorphous (i.e., non-crystalline) silica found in many common aggregates, given sufficient moisture.
In very old concrete where the calcium hydroxide has been leached from the leachate seepage path, the chemistry may revert to that similar to "speleothem" chemistry in limestone cave. [ 12 ] [ 13 ] This is where carbon dioxide enriched rain or seepage water forms a weak carbonic acid , which leaches calcium carbonate (CaCO 3 ) from within the ...
Alkali–aggregate reaction is a term mainly referring to a reaction which occurs over time in concrete between the highly alkaline cement paste and non-crystalline silicon dioxide, which is found in many common aggregates. This reaction can cause the expansion of the altered aggregate, leading to spalling and loss of strength of concrete.
There is often confusion between the meanings of the terms 'geopolymer cement' and 'geopolymer concrete'. A cement is a binder, whereas concrete is the composite material resulting from the mixing and hardening of cement with water (or an alkaline solution in the case of geopolymer cement), and stone aggregates.
Concrete is the most widely used material in existence and is behind only water as the planet's most-consumed resource. [ 2 ] Cements used in construction are usually inorganic , often lime - or calcium silicate -based, and are either hydraulic or less commonly non-hydraulic , depending on the ability of the cement to set in the presence of ...
Carbonatation is a slow process that occurs in concrete where lime (CaO, or Ca(OH) 2 ) in the cement reacts with carbon dioxide (CO 2) from the air and forms calcium carbonate. The water in the pores of Portland cement concrete is normally alkaline with a pH in the range of 12.5 to 13.5.
A fairly well-defined reaction front can often be observed in thin sections; ahead of the front the concrete is normal, or near normal. Behind the reaction front, the composition and the microstructure of concrete are modified. These changes may vary in type or severity but commonly include: Extensive cracking; Expansion
When water is added to cement, each of the compounds undergoes hydration and contributes to the final state of the concrete. [2] Only calcium silicates contribute to the strength. Tricalcium silicate is responsible for most of the early strength (first 7 days). [3] Dicalcium silicate, which reacts more slowly, only contributes to late strength.