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Where R is the ideal gas constant and γ is the ratio of specific heats (approximately 287 J/(kg·K) and 1.4 for air respectively). The pressure after the heat addition can be calculated from the ideal gas law: p 2 v 2 = R T 2 {\displaystyle p_{2}v_{2}=RT_{2}}
It is a physical constant that is featured in many fundamental equations in the physical sciences, such as the ideal gas law, the Arrhenius equation, and the Nernst equation . The gas constant is the constant of proportionality that relates the energy scale in physics to the temperature scale and the scale used for amount of substance.
The Van 't Hoff equation relates the change in the equilibrium constant, Keq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, ΔrH⊖, for the process. The subscript means "reaction" and the superscript means "standard". It was proposed by Dutch chemist Jacobus Henricus van 't Hoff in 1884 in his book ...
The temperature at which a chemical ignites decreases as the pressure is increased. Substances which spontaneously ignite in a normal atmosphere at naturally ambient temperatures are termed pyrophoric. Autoignition temperatures of liquid chemicals are typically measured using a 500-millilitre (18 imp fl oz; 17 US fl oz) flask placed in a ...
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
Mass diffusivity. Diffusivity, mass diffusivity or diffusion coefficient is usually written as the proportionality constant between the molar flux due to molecular diffusion and the negative value of the gradient in the concentration of the species. More accurately, the diffusion coefficient times the local concentration is the proportionality ...
For example, terrestrial air is primarily made up of diatomic gases (around 78% nitrogen, N 2, and 21% oxygen, O 2), and at standard conditions it can be considered to be an ideal gas. The above value of 1.4 is highly consistent with the measured adiabatic indices for dry air within a temperature range of 0–200 °C, exhibiting a deviation of ...
Expanded in this manner, the temperature of an ideal gas would remain constant, but the temperature of a real gas decreases, except at very high temperature. [10] The method of expansion discussed in this article, in which a gas or liquid at pressure P 1 flows into a region of lower pressure P 2 without significant change in kinetic energy, is ...
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