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Optical systems can be folded using plane mirrors; the system is still considered to be rotationally symmetric if it possesses rotational symmetry when unfolded. Any point on the optical axis (in any space) is an axial point. Rotational symmetry greatly simplifies the analysis of optical systems, which otherwise must be analyzed in three ...
F-center in an NaCl crystal. An F-center or color center or Farbe center (from the original German Farbzentrum, where Farbe means color and zentrum means center) is a type of crystallographic defect in which an anionic vacancy in a crystal lattice is occupied by one or more unpaired electrons.
Optical activity is measured using a polarized source and polarimeter. This is a tool particularly used in the sugar industry to measure the sugar concentration of syrup, and generally in chemistry to measure the concentration or enantiomeric ratio of chiral molecules in solution.
In optics, optical rotatory dispersion is the variation of the specific rotation of a medium with respect to the wavelength of light. Usually described by German physicist Paul Drude 's empirical relation: [ 1 ]
Recording optical rotation with a polarimeter: The plane of polarisation of plane polarised light (4) rotates (6) as it passes through an optically active sample (5). This angle is determined with a rotatable polarizing filter (7). In chemistry, specific rotation ([α]) is a property of a chiral chemical compound.
The optical properties of a material define how it interacts with light. The optical properties of matter are studied in optical physics (a subfield of optics ) and applied in materials science . The optical properties of matter include:
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...
The observed rotation of the sample is the weighted sum of the optical rotation of each anomer weighted by the amount of that anomer present. Therefore, one can use a polarimeter to measure the rotation of a sample and then calculate the ratio of the two anomers present from the enantiomeric excess, as long as one knows the rotation of each pure anomer.