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  2. Hypervalent molecule - Wikipedia

    en.wikipedia.org/wiki/Hypervalent_molecule

    For hypervalent compounds in which the ligands are more electronegative than the central, hypervalent atom, resonance structures can be drawn with no more than four covalent electron pair bonds and completed with ionic bonds to obey the octet rule. For example, in phosphorus pentafluoride (PF 5), 5 resonance structures can be generated each ...

  3. Octet rule - Wikipedia

    en.wikipedia.org/wiki/Octet_rule

    The bonding in carbon dioxide (CO 2): all atoms are surrounded by 8 electrons, fulfilling the octet rule.. The octet rule is a chemical rule of thumb that reflects the theory that main-group elements tend to bond in such a way that each atom has eight electrons in its valence shell, giving it the same electronic configuration as a noble gas.

  4. Resonance (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Resonance_(chemistry)

    Under the framework of valence bond theory, resonance is an extension of the idea that the bonding in a chemical species can be described by a Lewis structure. For many chemical species, a single Lewis structure, consisting of atoms obeying the octet rule, possibly bearing formal charges, and connected by bonds of positive integer order, is sufficient for describing the chemical bonding and ...

  5. Lewis structure - Wikipedia

    en.wikipedia.org/wiki/Lewis_structure

    "X" represents Hydrogen or Halogens. When Be is bonded with 2 other atoms, or when B and Al are bonded with 3 other atoms, they do not form full valence shells. Assume single bonds and use the actual bond number to calculate lone pairs. Expanded Octet (only occurs for elements in Groups 3-8)

  6. Electron deficiency - Wikipedia

    en.wikipedia.org/wiki/Electron_deficiency

    Alternatively, electron-deficiency describes molecules or ions that function as electron acceptors. Such electron-deficient species obey the octet rule, but they have (usually mild) oxidizing properties. [4] 1,3,5-Trinitrobenzene and related polynitrated aromatic compounds are often described as electron-deficient. [5]

  7. Electron counting - Wikipedia

    en.wikipedia.org/wiki/Electron_counting

    conclusion: Methane follows the octet-rule for carbon, and the duet rule for hydrogen, and hence is expected to be a stable molecule (as we see from daily life) H 2 S, for the central S; neutral counting: S contributes 6 electrons, each hydrogen radical contributes one each: 6 + 2 × 1 = 8 valence electrons

  8. VSEPR theory - Wikipedia

    en.wikipedia.org/wiki/VSEPR_theory

    The VSEPR theory can be extended to molecules with an odd number of electrons by treating the unpaired electron as a "half electron pair"—for example, Gillespie and Nyholm [8]: 364–365 suggested that the decrease in the bond angle in the series NO + 2 (180°), NO 2 (134°), NO −

  9. Oxyanion - Wikipedia

    en.wikipedia.org/wiki/Oxyanion

    4) ions can be found as such in various salts. Many oxyanions of elements in lower oxidation state obey the octet rule and this can be used to rationalize the formulae adopted. For example, chlorine(V) has two valence electrons so it can accommodate three electron pairs from bonds with oxide ions.