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  2. Catalytic reforming - Wikipedia

    en.wikipedia.org/wiki/Catalytic_reforming

    The heavy reformate is high in octane and low in benzene, hence it is an excellent blending component for the gasoline pool. Benzene is often removed with a specific operation to reduce the content of benzene in the reformate as the finished gasoline has often an upper limit of benzene content (in the UE this is 1% volume).

  3. Alkane metathesis - Wikipedia

    en.wikipedia.org/wiki/Alkane_metathesis

    These systems catalyze the conversion of ethane to give methane, propane and traces of butane. [1] Cross metathesis can also take place, for example methane and propane can react to give two molecules of ethane. Ethane reacts with toluene to give ethylbenzene and xylene. The reaction involves metallocyclobutane intermediates just as in olefin ...

  4. Van der Waals constants (data page) - Wikipedia

    en.wikipedia.org/wiki/Van_der_Waals_constants...

    The following table lists the Van der Waals constants (from the Van der Waals equation) for a number of common gases and volatile liquids. [ 1 ] To convert from L 2 b a r / m o l 2 {\displaystyle \mathrm {L^{2}bar/mol^{2}} } to L 2 k P a / m o l 2 {\displaystyle \mathrm {L^{2}kPa/mol^{2}} } , multiply by 100.

  5. Woodward–Hoffmann rules - Wikipedia

    en.wikipedia.org/wiki/Woodward–Hoffmann_rules

    Thermolysis converts 1 to (E,E) geometric isomer 2, but 3 to (E,Z) isomer 4.. The Woodward–Hoffmann rules (or the pericyclic selection rules) [1] are a set of rules devised by Robert Burns Woodward and Roald Hoffmann to rationalize or predict certain aspects of the stereochemistry and activation energy of pericyclic reactions, an important class of reactions in organic chemistry.

  6. Ethenone - Wikipedia

    en.wikipedia.org/wiki/Ethenone

    Ethenone is a highly reactive gas (at standard conditions) and has a sharp irritating odour.It is only reasonably stable at low temperatures (−80 °C). It must therefore always be prepared for each use and processed immediately, otherwise a dimerization to diketene occurs or it reacts to polymers that are difficult to handle.

  7. Petrochemical - Wikipedia

    en.wikipedia.org/wiki/Petrochemical

    Ammonia is used to make the fertilizer urea and methanol is used as a solvent and chemical intermediate. Methane, ethane, propane and butanes obtained primarily from natural gas processing plants. Methanol and formaldehyde. In 2007, the amounts of ethylene and propylene produced in steam crackers were about 115 Mt (megatonnes) and 70 Mt ...

  8. Transalkylation - Wikipedia

    en.wikipedia.org/wiki/Transalkylation

    Reaction of toluene to produce benzene and xylene. Transalkylation, as used by the petrochemical industry, is often used to convert toluene into benzene and xylenes. This is achieved through a disproportionation reaction of toluene in which one toluene molecule transfers its methyl group to another one. The reaction is not selective, and the ...

  9. Hydrogenation - Wikipedia

    en.wikipedia.org/wiki/Hydrogenation

    These details are revealed in part using D 2 (deuterium), because recovered alkenes often contain deuterium. For aromatic substrates, the first hydrogenation is slowest. The product of this step is a cyclohexadiene, which hydrogenate rapidly and are rarely detected. Similarly, the cyclohexene is ordinarily reduced to cyclohexane.