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Isobutylene (or 2-methylpropene) is a hydrocarbon with the chemical formula (CH 3) 2 C=CH 2. It is a four-carbon branched alkene (olefin), one of the four isomers of butylene . It is a colorless flammable gas, and is of considerable industrial value.
Butyl rubber, sometimes just called "butyl", is a synthetic rubber, a copolymer of isobutylene with isoprene. The abbreviation IIR stands for isobutylene isoprene rubber. Polyisobutylene, also known as "PIB" or polyisobutene, (C 4 H 8) n, is the homopolymer of isobutylene, or 2-methyl-1-propene, on which butyl rubber is based. Butyl rubber is ...
The tert-butyl substituent is very bulky and is used in chemistry for kinetic stabilization, as are other bulky groups such as the related trimethylsilyl group. The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below.
Butene, also known as butylene, is an alkene with the formula C 4 H 8.The word butene may refer to any of the individual compounds. They are colourless gases that are present in crude oil as a minor constituent in quantities that are too small for viable extraction.
Isobutylene can be produced through a variety of methods. n-butane can be isomerized into isobutane which can be dehydrogenated to isobutylene. [7] In the Halcon process, t-Butyl hydroperoxide derived from isobutane oxygenation is treated with propylene to produce propylene oxide and t-butanol. The t-butanol can be dehydrated to isobutylene.
Polyisobutene (polyisobutylene) is a class of organic polymers prepared by polymerization of isobutene.The polymers often have the formula Me 3 C[CH 2 CMe 2] n H (Me = CH 3).They are typically colorless gummy solids.
This colorless gas is structurally similar to isobutylene. It is used as a comonomer in the production of modified polyvinylidene fluoride. It is produced in a multistep process starting with the reaction of acetic anhydride with hexafluoroacetone. [1] It is oxidized by sodium hypochlorite to hexafluoroisobutylene oxide.
Illustrative is the conversion of isobutylene to tert-butylamine using HCN and sulfuric acid followed by base neutralization. The weight of the salt byproduct is greater than the weight of the amine. [12] In the laboratory, the Ritter reaction suffers from the necessity of an extremely strong acid catalyst.