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Hypochlorous acid is an inorganic compound with the chemical formula Cl O H, also written as HClO, HOCl, or ClHO. [ 2 ] [ 3 ] Its structure is H−O−Cl . It is an acid that forms when chlorine dissolves in water , and itself partially dissociates , forming a hypochlorite anion , ClO − .
Chlorous acid is an inorganic compound with the formula HClO 2. It is a weak acid. Chlorine has oxidation state +3 in this acid. The pure substance is unstable, disproportionating to hypochlorous acid (Cl oxidation state +1) and chloric acid (Cl oxidation state +5): 2 HClO 2 → HClO + HClO 3
For example, aqueous perchloric acid (HClO 4), aqueous hydrochloric acid (HCl) and aqueous nitric acid (HNO 3) are all completely ionized, and are all equally strong acids. [ 3 ] Similarly, when ammonia is the solvent, the strongest acid is ammonium (NH 4 + ), thus HCl and a super acid exert the same acidifying effect.
For example, acetic acid is a weak acid which has a = 1.75 x 10 −5. Its conjugate base is the acetate ion with K b = 10 −14 /K a = 5.7 x 10 −10 (from the relationship K a × K b = 10 −14), which certainly does not correspond to a strong base. The conjugate of a weak acid is often a weak base and vice versa.
Because the solvent system definition depends on the solute as well as on the solvent itself, a particular solute can be either an acid or a base depending on the choice of the solvent: HClO 4 is a strong acid in water, a weak acid in acetic acid, and a weak base in fluorosulfonic acid; this characteristic of the theory has been seen as both a ...
On the other hand, if a chemical is a weak acid its conjugate base will not necessarily be strong. Consider that ethanoate, the conjugate base of ethanoic acid, has a base splitting constant (Kb) of about 5.6 × 10 −10, making it a weak base. In order for a species to have a strong conjugate base it has to be a very weak acid, like water.
It may be produced from barium chlorate through its reaction with sulfuric acid, which results in a solution of chloric acid and insoluble barium sulfate precipitate: [2] Ba(ClO 3) 2 + H 2 SO 4 → 2 HClO 3 + BaSO 4. The chlorate must be dissolved in boiling water and the acid should be somewhat diluted in water and heated before mixing.
Nevertheless, perchloric acid (HClO 4), sulfuric acid (H 2 SO 4), and nitric acid (HNO 3) are a few common oxyacids that are relatively easily prepared as pure substances. Imidic acids are created by replacing =O with =NR in an oxyacid.