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The nitro group is one of the most common explosophores (functional group that makes a compound explosive) used globally. The nitro group is also strongly electron-withdrawing. Because of this property, C−H bonds alpha (adjacent) to the nitro group can be acidic. For similar reasons, the presence of nitro groups in aromatic compounds retards ...
A nitroalkene, or nitro olefin, is a functional group combining the functionality of its constituent parts, an alkene and nitro group, while displaying its own chemical properties through alkene activation, making the functional group useful in specialty reactions such as the Michael reaction or Diels-Alder additions.
The reduction of nitro compounds are chemical reactions of wide interest in organic chemistry. The conversion can be effected by many reagents. The nitro group was one of the first functional groups to be reduced. Alkyl and aryl nitro compounds behave differently. Most useful is the reduction of aryl nitro compounds.
Commonly, 2-nitrochlorobenzene is treated with ammonia to generate 2-nitroaniline, whose nitro group is then reduced: [4] ClC 6 H 4 NO 2 + 2 NH 3 → H 2 NC 6 H 4 NO 2 + NH 4 Cl H 2 NC 6 H 4 NO 2 + 3 H 2 → H 2 NC 6 H 4 NH 2 + 2 H 2 O
In organic chemistry, nitration is a general class of chemical processes for the introduction of a nitro group (−NO 2) into an organic compound.The term also is applied incorrectly to the different process of forming nitrate esters (−ONO 2) between alcohols and nitric acid (as occurs in the synthesis of nitroglycerin).
The nitro group in the molecule serves as an electron withdrawing group that makes the molecule a good candidate as a dienophile. It readily forms an adduct with cyclopentadiene, spiroheptadiene, and their derivatives in a [4+2] cycloaddition. [1] Nitroethene can react at the 2π electron source in a [3+2] cycloaddition with nitrones. [5] [6]
Nitroalkene, a functional group combining the functionality of an alkene and nitro group; Nitrocellulose, or cellulose nitrate, an extremely flammable chemical compound; Nitroglycerin, or glyceryl trinitrate, an explosive chemical compound; Nitromethane, a simple organic nitro compound with the formula CH 3 NO 2. Nitro fuel, a fuel containing ...
Structure of the nitroamino group, > N−NO 2, here bonded to two R groups. In organic and inorganic chemistry, nitroamines or nitramides are chemical compounds with the general chemical structure R 1 R 2 N−NO 2. They consist of a nitro group (−NO 2) bonded to the nitrogen of an amine.