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Manganese(III) oxide is a chemical compound with the formula Mn 2 O 3. It occurs in nature as the mineral bixbyite (recently changed to bixbyite-(Mn) [ 3 ] [ 4 ] ) and is used in the production of ferrites and thermistors .
Manganese(II,III) oxide is the chemical compound with formula Mn 3 O 4. Manganese is present in two oxidation states +2 and +3 and the formula is sometimes written as MnO · Mn 2 O 3 . Mn 3 O 4 is found in nature as the mineral hausmannite .
Manganese oxide is any of a variety of manganese oxides and hydroxides. [1] These include Manganese(II) oxide, MnO; Manganese(II,III) oxide, Mn 3 O 4; Manganese(III) oxide, Mn 2 O 3; Manganese dioxide, MnO 2; Manganese(VI) oxide, MnO 3; Manganese(VII) oxide, Mn 2 O 7; Other manganese oxides include Mn 5 O 8, Mn 7 O 12 and Mn 7 O 13.
Manganese(IV) oxide was used in the original type of dry cell battery as an electron acceptor from zinc, and is the blackish material in carbon–zinc type flashlight cells. The manganese dioxide is reduced to the manganese oxide-hydroxide MnO(OH) during discharging, preventing the formation of hydrogen at the anode of the battery. [82]
Hausmannite is a complex oxide, or a mixed oxide, of manganese containing both di-and tri-valent manganese. Its chemical formula can be represented as Mn II Mn III 2 O 4, or more simply noted as MnO·Mn 2 O 3, or Mn 3 O 4, as commonly done for magnetite (Fe 3 O 4), the corresponding iron oxide. It belongs to the spinel group and forms ...
The data below tabulates standard electrode potentials (E°), in volts relative to the standard hydrogen electrode (SHE), at: . Temperature 298.15 K (25.00 °C; 77.00 °F); ...
The distortions and deviation from truly planar metal oxide layers are a manifestation of the electronic configuration of the Mn(III) Jahn-Teller ion. [12] A layered variant, isostructural with LiCoO 2 , was prepared in 1996 by ion exchange from the layered compound NaMnO 2 , [ 13 ] however long term cycling and the defect nature of the charged ...
The main factor affecting rates is charge: highly charged metal aquo cations exchange their water more slowly than singly charged cations. Thus, the exchange rates for [Na(H 2 O) 6 ] + and [Al(H 2 O) 6 ] 3+ differ by a factor of 10 9 .