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When a paint coating is applied on a metallic surface contaminated with soluble salts, an osmotic blistering process takes place (Figure 8.10). Osmosis is the spontaneous net movement of solvent molecules (water) through a semipermeable membrane (coating film) into a region of higher solute concentration (the salt contaminated substrate).
Example of flat piece of concrete having dislodged with corroded rebar underneath, Welland River bridge across Queen Elizabeth Way in Niagara Falls, Ontario. The expansion of the corrosion products (iron oxides) of carbon steel reinforcement structures may induce internal mechanical stress (tensile stress) that cause the formation of cracks and disrupt the concrete structure.
In corrosion, spalling occurs when a substance (metal or concrete) sheds tiny particles of corrosion products as the corrosion reaction progresses. Although they are not soluble or permeable, these corrosion products do not adhere to the parent material's surface to form a barrier to further corrosion, as happens in passivation. Spallation ...
Concrete sealers are applied to concrete to protect it from surface damage, corrosion, and staining. They either block the pores in the concrete to reduce absorption of water and salts or form an impermeable layer which prevents such materials from passing.
Cathodic protection (CP; / k æ ˈ θ ɒ d ɪ k / ⓘ) is a technique used to control the corrosion of a metal surface by making it the cathode of an electrochemical cell. [1] A simple method of protection connects the metal to be protected to a more easily corroded " sacrificial metal " to act as the anode .
Fretting refers to wear and sometimes corrosion damage of loaded surfaces in contact while they encounter small oscillatory movements tangential to the surface. Fretting is caused by adhesion of contact surface asperities, which are subsequently broken again by the small movement. This breaking causes wear debris to be formed.
The initiation time is related to the rate at which carbonation propagates in the concrete cover thickness.Once that carbonation reaches the steel surface, altering the local pH value of the environment, the protective thin film of oxides on the steel surface becomes instable, and corrosion initiates involving an extended portion of the steel surface.
In sewerage areas where biogenic sulfide corrosion is expected, acid-resistant materials like calcium aluminate cements, PVC or vitrified clay pipe may be substituted to ordinary concrete or steel sewers. Existing structures that have extensive exposure to biogenic corrosion such as sewer manholes and pump station wet wells can be rehabilitated.