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Polyhedral representation of spinel MgAl 2 O 4. Spinel (/ s p ɪ ˈ n ɛ l, ˈ s p ɪ n əl / [7]) is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula MgAl 2 O 4 in the cubic crystal system. Its name comes from the Latin word spinella, a diminutive form of spine, in reference to its pointed crystals. [5]
Taaffeite (/ ˈ t ɑː f aɪ t /; BeMgAl 4 O 8) is a mineral, named after its discoverer Richard Taaffe (1898–1967) who found the first sample, a cut and polished gem, in October 1945 in a jeweler's shop in Dublin, Ireland. [4] [5] As such, it is the only gemstone to have
A common cause is oriented sub-microscopic crystals of rutile within the gem mineral. It occurs in rubies, sapphires, garnet, diopside, and spinel when a cabochon is cut from a suitable stone. Star sapphires and rubies display the property from titanium dioxide impurities present in them. [2]
Ceylonite, named for the island of Ceylon, is a ferroan spinel with Mg:Fe from 3:1 and 1:1, and little or no ferric iron. Pleonaste is named from the Greek for 'abundant,' for its many crystal forms, and is distinguished chemically by low Mg:Fe ratios of approximately 1:3. It is sometimes used as a gemstone. [2]
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An example of an inverse spinel is Fe 3 O 4, if the Fe 2+ (A 2+) ions are d 6 high-spin and the Fe 3+ (B 3+) ions are d 5 high-spin. In addition, intermediate cases exist where the cation distribution can be described as (A 1− x B x )[A x ⁄ 2 B 1− x ⁄ 2 ] 2 O 4 , where parentheses () and brackets [] are used to denote tetrahedral and ...
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Samarian Spinel, the world's largest spinel; Menshikov Ruby, the world's second largest spinel set on top of the Great Imperial Crown of Russia; Timur Ruby, believed to be a ruby until 1851, hence its name; Black Prince's Ruby, the famous spinel mounted on the Imperial State Crown of the United Kingdom