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Elemental iron is virtually absent on the Earth's surface except as iron-nickel alloys from meteorites and very rare forms of deep mantle xenoliths.Although iron is the fourth most abundant element in Earth's crust, composing about 5% by weight, [4] the vast majority is bound in silicate or, more rarely, carbonate minerals, and smelting pure iron from these minerals would require a prohibitive ...
The gray spheres are oxygen, green are divalent iron, blue are trivalent iron. Also shown are an iron atom in an octahedral space (light blue) and another in a tetrahedral space (gray). Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe 2+ Fe 3+ 2 O 4.
Iron shows the characteristic chemical properties of the transition metals, namely the ability to form variable oxidation states differing by steps of one and a very large coordination and organometallic chemistry: indeed, it was the discovery of an iron compound, ferrocene, that revolutionalized the latter field in the 1950s. [59]
Iron ore was also used as a flux in the smelting of copper. These agents served various functions, the simplest being a reducing agent, which prevented oxides from forming on the surface of the molten metal, while others absorbed impurities into slag , which could be scraped off molten metal.
Siderite is a mineral composed of iron(II) carbonate (FeCO 3).Its name comes from the Ancient Greek word σίδηρος (sídēros), meaning "iron".A valuable iron ore, it consists of 48% iron and lacks sulfur and phosphorus.
Limonite (/ ˈ l aɪ m ə ˌ n aɪ t /) is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as FeO(OH)·nH 2 O, although this is not entirely accurate as the ratio of oxide to hydroxide can vary quite widely.
Iron(II) chloride tetrahydrate, FeCl 2 ·4H 2 O. In chemistry, iron(II) refers to the element iron in its +2 oxidation state. The adjective ferrous or the prefix ferro-is often used to specify such compounds, as in ferrous chloride for iron(II) chloride (FeCl 2). The adjective ferric is used instead for iron(III) salts, containing the cation Fe 3+.
Hematite is not only harder than pure iron, but also much more brittle. The term kidney ore may be broadly used to describe botryoidal, mammillary, or reniform hematite. [8] Maghemite is a polymorph of hematite (γ-Fe 2 O 3) with the same chemical formula, but with a spinel structure like magnetite.