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NCCl + CH 3 CN → NCCH 2 CN + HCl. About 20,000,000 kg are produced annually (2007). Important outlets include the synthesis of thiamine, the drug triamterene and minoxidil, and the dyes disperse Yellow 90 and disperse Blue 354. [4] Malononitrile is relatively acidic, with a pK a of 11 in water. [5]
Like most azobenzenes, Solvent Yellow 7 can be synthesized by the reaction of the phenyldiazonium salt with phenol.The optimal pH value for this azo coupling is 8.5-10. The reaction is carried out in water, since sodium chloride (or potassium chloride) formed in the reaction is soluble in water, while the product precipitates.
Carbonyl cyanide m-chlorophenyl hydrazone (CCCP; also known as [(3-chlorophenyl)hydrazono]malononitrile) is a chemical inhibitor of oxidative phosphorylation. It is a nitrile , hydrazone and protonophore .
o-Phenylenediamine (OPD) is an organic compound with the formula C 6 H 4 (NH 2) 2. This aromatic diamine is an important precursor to many heterocyclic compounds. OPD is a white compound although samples appear darker owing to oxidation by air. It is isomeric with m-phenylenediamine and p-phenylenediamine.
TCNE is prepared by brominating malononitrile in the presence of potassium bromide to give the KBr-complex, and dehalogenating with copper. [1] Oxidation of TCNE with hydrogen peroxide gives the corresponding epoxide, which has unusual properties. [2] In the presence of base, TCNE reacts with malononitrile to give salts of pentacyanopropenide: [3]
Methyl yellow, or C.I. 11020, is an organic compound with the formula C 6 H 5 N 2 C 6 H 4 N(CH 3) 2. It is an azo dye derived from dimethylaniline. It is a yellow solid. According to X-ray crystallography, the C 14 N 3 core of the molecule is planar. [3] It is used as a dye for plastics and may be used as a pH indicator.
2-Phenylphenol, or o-phenylphenol, is an organic compound. In terms of structure, it is one of the monohydroxylated isomers of biphenyl. [2] [3] It is a white solid. It is a biocide used as a preservative with E number E231 and under the trade names Dowicide, Torsite, Fungal, Preventol, Nipacide and many others.
There are three structural isomers: 1,2-dihydroxybenzene (the ortho isomer) is commonly known as catechol, 1,3-dihydroxybenzene (the meta isomer) is commonly known as resorcinol, and 1,4-dihydroxybenzene (the para isomer) is commonly known as hydroquinone. [1]