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A single-displacement reaction, also known as single replacement reaction or exchange reaction, is an archaic concept in chemistry. It describes the stoichiometry of some chemical reactions in which one element or ligand is replaced by atom or group. [1] [2] [3] It can be represented generically as:
A substitution reaction (also known as single displacement reaction or single substitution reaction) is a chemical reaction during which one functional group in a chemical compound is replaced by another functional group. [1] Substitution reactions are of prime importance in organic chemistry.
Reactions often consist of a sequence of individual sub-steps, the so-called elementary reactions, and the information on the precise course of action is part of the reaction mechanism. Chemical reactions are described with chemical equations , which symbolically present the starting materials, end products, and sometimes intermediate products ...
Castigliano's method for calculating displacements is an application of his second theorem, which states: If the strain energy of a linearly elastic structure can be expressed as a function of generalised force Q i then the partial derivative of the strain energy with respect to generalised force gives the generalised displacement q i in the direction of Q i.
The equation is given by ¨ + ˙ + + = (), where the (unknown) function = is the displacement at time t, ˙ is the first derivative of with respect to time, i.e. velocity, and ¨ is the second time-derivative of , i.e. acceleration.
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The first step when using the direct stiffness method is to identify the individual elements which make up the structure. Once the elements are identified, the structure is disconnected at the nodes, the points which connect the different elements together. Each element is then analyzed individually to develop member stiffness equations.