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  2. Bromocyclohexane - Wikipedia

    en.wikipedia.org/wiki/Bromocyclohexane

    C 6 H 11 Br Molar mass: 163.06 g/mol Appearance colorless liquid Density: 1.324 g/cm 3: Melting point: −57 °C (−71 °F; 216 K) Boiling point: 166 to 167 °C (331 to 333 °F; 439 to 440 K) Hazards Flash point: 62.8 °C (145.0 °F; 335.9 K) Related compounds

  3. Büchner–Curtius–Schlotterbeck reaction - Wikipedia

    en.wikipedia.org/wiki/Büchner–Curtius...

    Additionally, the reactivity of two series of ketones are in the orders Cl 3 CCOCH 3 > CH 3 COCH 3 > C 6 H 5 COCH 3 and cyclohexanone > cyclopentanone > cycloheptanone > cyclooctanone. [7] [8] These orders of reactivity are the same as those observed for reactions that are well established as proceeding through nucleophilic attack on a carbonyl ...

  4. Bretherick's Handbook of Reactive Chemical Hazards

    en.wikipedia.org/wiki/Bretherick's_Handbook_of...

    Bretherick’s Handbook of Reactive Chemical Hazards is a well-established source of information on chemical safety, often known by its author’s name, and often cited in the chemical and chemical engineering literature. In recent editions it has been in two volumes, volume 1 being individual compounds and hazardous reactions, volume 2 being ...

  5. Suzuki reaction - Wikipedia

    en.wikipedia.org/wiki/Suzuki_reaction

    The Suzuki reaction or Suzuki coupling is an organic reaction that uses a palladium complex catalyst to cross-couple a boronic acid to an organohalide. [1] [2] [3] It was first published in 1979 by Akira Suzuki, and he shared the 2010 Nobel Prize in Chemistry with Richard F. Heck and Ei-ichi Negishi for their contribution to the discovery and development of noble metal catalysis in organic ...

  6. Curtin–Hammett principle - Wikipedia

    en.wikipedia.org/wiki/Curtin–Hammett_principle

    The Curtin–Hammett principle is a principle in chemical kinetics proposed by David Yarrow Curtin and Louis Plack Hammett.It states that, for a reaction that has a pair of reactive intermediates or reactants that interconvert rapidly (as is usually the case for conformational isomers), each going irreversibly to a different product, the product ratio will depend both on the difference in ...

  7. Michaelis–Arbuzov reaction - Wikipedia

    en.wikipedia.org/wiki/Michaelis–Arbuzov_reaction

    [5] Phosphonites are generally more reactive than phosphite esters. They react to produce phosphinates. Heating is also required for the reaction, but pyrolysis of the ester to an acid is a common side reaction. The poor availability of substituted phosphonites limits the usage of this class of reagent in the Arbuzov reaction.

  8. 5 reasons to eat more cherries, from improving sleep to ... - AOL

    www.aol.com/lifestyle/5-reasons-eat-more...

    One cup (138 grams) of cherries with pits contains about 87 calories, 22 grams of carbohydrates, 19 grams of natural sugar, 3 grams of fiber, 1.5 grams of protein and almost no fat.

  9. Chemoselectivity - Wikipedia

    en.wikipedia.org/wiki/Chemoselectivity

    The carbon-bromine bond is more reactive than the carbon-fluorine bond. If a molecule has several potential reactive sites, the reaction will occur in the most reactive one. When comparing carbon-halogen bonds, lighter halogens such as fluorine and chlorine have a better orbital overlap with carbon, which makes the bond stronger. [4]