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Propane may be the most suitable for high temperature heat pumps. [74] Ammonia (R717) and carbon dioxide also have a low GWP. As of 2023 smaller CO 2 heat pumps are not widely available and research and development of them continues. [75] A 2024 report said that refrigerants with GWP are vulnerable to further international restrictions. [76]
Thermodynamic heat pump cycles or refrigeration cycles are the conceptual and mathematical models for heat pump, air conditioning and refrigeration systems. [1] A heat pump is a mechanical system that transmits heat from one location (the "source") at a certain temperature to another location (the "sink" or "heat sink") at a higher temperature. [2]
For low-temperature heat sources of 15–25 °C, driven by a small amount of high-temperature heat sources (such as high-temperature steam or direct combustion), cold water at a temperature of 7–15 °C and hot water at a temperature above 47 °C can be prepared. 1.2, >1.5 when heating. [4]
The EU standard test conditions for an air source heat pump is at dry-bulb temperature of 20 °C (68 °F) for and 7 °C (44.6 °F) for . [9] Given sub-zero European winter temperatures, real world heating performance is significantly poorer than such standard COP figures imply.
The heat pump's performance is limited by the Carnot cycle and will approach 1.0 as the outdoor-to-indoor temperature difference increases, which for most air source heat pumps happens as outdoor temperatures approach −18 °C (0 °F).
"Cold climate" heat pumps are designed to optimize efficiency below 0 °F (−18 °C). As of 2023 heat pumps are marketed that will extract heat from outdoor temperatures as low as −40 °F (−40 °C). In the case of cold climates, water or ground-source heat pumps are often the most efficient solution.
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