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Fluorine's chemistry is dominated by its strong tendency to gain an electron. It is the most electronegative element and elemental fluorine is a strong oxidant. The removal of an electron from a fluorine atom requires so much energy that no known reagents are known to oxidize fluorine to any positive oxidation state. [20]
As an approximate rule, electron configurations are given by the Aufbau principle and the Madelung rule. However there are numerous exceptions; for example the lightest exception is chromium, which would be predicted to have the configuration 1s 2 2s 2 2p 6 3s 2 3p 6 3d 4 4s 2 , written as [Ar] 3d 4 4s 2 , but whose actual configuration given ...
Clean ionic bonding — in which one atom or molecule completely transfers an electron to another — cannot exist: all ionic compounds have some degree of covalent bonding or electron sharing. Thus, the term "ionic bonding" is given when the ionic character is greater than the covalent character – that is, a bond in which there is a large ...
Chromium and copper have electron configurations [Ar] 3d 5 4s 1 and [Ar] 3d 10 4s 1 respectively, i.e. one electron has passed from the 4s-orbital to a 3d-orbital to generate a half-filled or filled subshell. In this case, the usual explanation is that "half-filled or completely filled subshells are particularly stable arrangements of electrons".
Electron transfer between lithium (Li) and fluorine (F). Forming an ionic bond, Li and F become Li + and F − ions.. An ion (/ ˈ aɪ. ɒ n,-ən /) [1] is an atom or molecule with a net electrical charge.
The factors that determine the type of chemical bond are the Laplacian and the electron density at the bond critical point. At the bond critical point a typical covalent bond has significant density and a large negative Laplacian. In contrast a "closed shell" interaction as in an ionic bond has a small electron density and a positive Laplacian. [2]
Fluorine's first ionization energy is third-highest among all elements, behind helium and neon, [16] which complicates the removal of electrons from neutral fluorine atoms. It also has a high electron affinity, second only to chlorine, [17] and tends to capture an electron to become isoelectronic with the noble gas neon; [3] it has the highest ...
In terms of Lewis structures, formal charge is used in the description, comparison, and assessment of likely topological and resonance structures [7] by determining the apparent electronic charge of each atom within, based upon its electron dot structure, assuming exclusive covalency or non-polar bonding.