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Pressure dependence of the water ionization constant at 25 °C. In general, ionization in aqueous solutions tends to increase with increasing pressure. In a condensed phase, the pressure dependence of the equilibrium constant is associated with the reaction volume. [18] For reaction: α A + β B ⇌ σ S + τ T. the reaction volume is:
However, a "salting in" effect has also been observed, for example for the effective Henry's law constant of glyoxal. The effect can be described with the Sechenov equation, named after the Russian physiologist Ivan Sechenov (sometimes the German transliteration "Setschenow" of the Cyrillic name Се́ченов is used). There are many ...
A diffuser is "a device for reducing the velocity and increasing the static pressure of a fluid passing through a system”. [1] The fluid's static pressure rise as it passes through a duct is commonly referred to as pressure recovery. In contrast, a nozzle is used to increase the discharge velocity and lower the pressure of a fluid passing ...
The system tries to counteract the decrease in partial pressure of gas molecules by shifting to the side that exerts greater pressure. Similarly, if we were to increase pressure by decreasing volume, the equilibrium shifts to the right, counteracting the pressure increase by shifting to the side with fewer moles of gas that exert less pressure.
where ln denotes the natural logarithm, is the thermodynamic equilibrium constant, and R is the ideal gas constant.This equation is exact at any one temperature and all pressures, derived from the requirement that the Gibbs free energy of reaction be stationary in a state of chemical equilibrium.
A system in contact equilibrium with another system can by a thermodynamic operation be isolated, and upon the event of isolation, no change occurs in it. A system in a relation of contact equilibrium with another system may thus also be regarded as being in its own state of internal thermodynamic equilibrium.
The change in pressure over distance dx is dp and flow velocity v = dx / dt . Apply Newton's second law of motion (force = mass × acceleration) and recognizing that the effective force on the parcel of fluid is −A dp. If the pressure decreases along the length of the pipe, dp is negative but the force resulting in flow is positive ...
Choked flow is a limiting condition where the mass flow cannot increase with a further decrease in the downstream pressure environment for a fixed upstream pressure and temperature. For homogeneous fluids, the physical point at which the choking occurs for adiabatic conditions is when the exit plane velocity is at sonic conditions; i.e., at a ...