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Manganese carbonate is a compound with the chemical formula Mn CO 3. Manganese carbonate occurs naturally as the mineral rhodochrosite but it is typically produced industrially. It is a pale pink, water-insoluble solid. Approximately 20,000 metric tonnes were produced in 2005. [3]
Rhodochrosite forms a complete solid solution series with iron carbonate . Calcium (as well as magnesium and zinc, to a limited extent) frequently substitutes for manganese in the structure, leading to lighter shades of red and pink, depending on the degree of substitution. This is the reason for the rose color of rhodochrosite.
Manganese(IV) oxide (manganese dioxide, MnO 2) is used as a reagent in organic chemistry for the oxidation of benzylic alcohols (where the hydroxyl group is adjacent to an aromatic ring). Manganese dioxide has been used since antiquity to oxidize and neutralize the greenish tinge in glass from trace amounts of iron contamination. [45]
Manganese dioxide is the inorganic compound with the formula MnO 2 . This blackish or brown solid occurs naturally as the mineral pyrolusite , which is the main ore of manganese and a component of manganese nodules .
Kutnohorite is a rare calcium manganese carbonate mineral with magnesium and iron that is a member of the dolomite group. It forms a series with dolomite, and with ankerite.The end member formula is CaMn 2+ (CO 3) 2, [6] but Mg 2+ and Fe 2+ commonly substitute for Mn 2+, with the manganese content varying from 38% to 84%, [2] so the formula Ca(Mn 2+,Mg,Fe 2+)(CO 3) 2 better represents the species.
In enzymology, a manganese peroxidase (EC 1.11.1.13) is an enzyme that catalyzes the chemical reaction. 2 Mn(II) + 2 H + + H 2 O 2 2 Mn(III) + 2 H 2 O. The 3 substrates of this enzyme are Mn(II), H +, and H 2 O 2, whereas its two products are Mn(III) and H 2 O.
Manganese(II) chloride is the dichloride salt of manganese, MnCl 2. This inorganic chemical exists in the anhydrous form, as well as the di hydrate (MnCl 2 ·2H 2 O) and tetrahydrate (MnCl 2 ·4H 2 O), with the tetrahydrate being the most common form.
Manganese(II) sulfate usually refers to the inorganic compound with the formula MnSO 4 ·H 2 O. This pale pink deliquescent solid is a commercially significant manganese(II) salt. Approximately 260,000 tonnes of manganese(II) sulfate were produced worldwide in 2005.