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Phenylpropanoic acid or hydrocinnamic acid is a carboxylic acid with the formula C 9 H 10 O 2 belonging to the class of phenylpropanoids. It is a white, crystalline solid with a sweet, floral scent at room temperature. Phenylpropanoic acid has a wide variety of uses including cosmetics, food additives, and pharmaceuticals. [5]
In chemistry, the hydrogenation of carbon–nitrogen double bonds is the addition of the elements of dihydrogen (H 2) across a carbon–nitrogen double bond, forming amines or amine derivatives. [1] Although a variety of general methods have been developed for the enantioselective hydrogenation of ketones, [ 2 ] methods for the hydrogenation of ...
Hydroxylation of cinnamic acid in the 4-position by trans-cinnamate 4-monooxygenase leads to p-coumaric acid, which can be further modified into hydroxylated derivatives such as umbelliferone. Another use of p -coumaric acid via its thioester with coenzyme A , i.e. 4-coumaroyl-CoA , is the production of chalcones .
Chromic acid oxidizes it to benzoic acid; zinc and acetic acid reduce it to cinnamic acid, C 6 H 5 CH=CHCO 2 H, whilst sodium amalgam reduces it to hydrocinnamic acid, C 6 H 5 CH 2 CH 2 CO 2 H. Ortho-nitrophenylpropiolic acid, NO 2 C 6 H 4 CCCO 2 H, prepared by the action of alcoholic potash on ortho-nitrocinnamic acid dibromide, crystallizes ...
Phenylpropanoic acid Index of chemical compounds with the same molecular formula This set index page lists chemical structure articles associated with the same molecular formula .
The catalyst is also used for the hydrogenolysis of phenyl phosphate esters, a reaction that does not occur with palladium catalysts. The pH of the solvent significantly affects the reaction course, and reactions of the catalyst are often enhanced by conducting the reduction in neat acetic acid, or solutions of acetic acid in other solvents.
Two broad strategies exist for carbonyl reduction. One method, which is favored in industry, uses hydrogen as the reductant. This approach is called hydrogenation and requires metal catalysts. The other broad approach employs stoichiometric reagents that deliver H − and H + separately. This article focuses on the use of these reagents.
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