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[5] 2,4,6-tri-tert-butylphenol is also found as a by-product in the synthesis of the disubstitution products 2,4-DTBP and 2,6-DTBP, which are more widely used antioxidants. [2] Synthese von 2,4,6-Tri-tert-butylphenol mit Isobuten. A synthesis of 2,4,6-tri-tert-butylphenol has been described that is also suitable as a teaching experiment.
tert-Butyl alcohol is deprotonated with a strong base to give the alkoxide. Particularly common is potassium tert-butoxide, which is prepared by treating tert-butanol with potassium metal. [8] K + t-BuOH → t-BuO − K + + 1 / 2 H 2. The tert-butoxide is a strong, non-nucleophilic base in organic chemistry.
For this reason di-tert-butyl peroxide is commonly used as a radical initiator in organic synthesis and polymer chemistry. The decomposition reaction proceeds via the generation of methyl radicals. (CH 3) 3 COOC(CH 3) 3 → 2 (CH 3) 3 CO • (CH 3) 3 CO • → (CH 3) 2 CO + CH • 3 2 CH • 3 → C 2 H 6
The chemical synthesis of BHT in industry has involved the reaction of p-cresol (4-methylphenol) with isobutylene (2-methylpropene), catalyzed by sulfuric acid: [11] CH 3 (C 6 H 4)OH + 2 CH 2 =C(CH 3) 2 → ((CH 3) 3 C) 2 CH 3 C 6 H 2 OH. Alternatively, BHT has been prepared from 2,6-di-tert-butylphenol by hydroxymethylation or aminomethylation ...
The process of making a diet version of a food usually requires finding an adequate low-food-energy substitute for some high-food-energy ingredient. [2] This can be as simple as replacing some or all of the food's sugar with a sugar substitute as is common with diet soft drinks such as Coca-Cola (for example Diet Coke). In some snacks, the food ...
Methyl tert-butyl ether (MTBE), also known as tert-butyl methyl ether, is an organic compound with a structural formula (CH 3) 3 COCH 3. MTBE is a volatile, flammable, and colorless liquid that is sparingly soluble in water. [ 1 ]
4-tert-Butylcatechol (TBC) is an organic chemical compound which is a derivative of catechol. [1] TBC is available in the form of a solid crystal flake [ 2 ] and 85% solution in methanol [ 3 ] or water.
tert-Butylthiol is the main ingredient in many gas odorant blends. [citation needed] It is always utilized as a blend of other compounds, typically dimethyl sulfide, methyl ethyl sulfide, tetrahydrothiophene or other mercaptans such as isopropyl mercaptan, sec-butyl mercaptan and/or n-butyl mercaptan, due to its rather high melting point of −0.5 °C (31.1 °F).