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  2. Rate-determining step - Wikipedia

    en.wikipedia.org/wiki/Rate-determining_step

    As an example, consider the gas-phase reaction NO 2 + CO → NO + CO 2.If this reaction occurred in a single step, its reaction rate (r) would be proportional to the rate of collisions between NO 2 and CO molecules: r = k[NO 2][CO], where k is the reaction rate constant, and square brackets indicate a molar concentration.

  3. Limiting reagent - Wikipedia

    en.wikipedia.org/wiki/Limiting_reagent

    The limiting reagent must be identified in order to calculate the percentage yield of a reaction since the theoretical yield is defined as the amount of product obtained when the limiting reagent reacts completely.

  4. Observational error - Wikipedia

    en.wikipedia.org/wiki/Observational_error

    Some errors are not clearly random or systematic such as the uncertainty in the calibration of an instrument. [4] Random errors or statistical errors in measurement lead to measurable values being inconsistent between repeated measurements of a constant attribute or quantity are taken. Random errors create measurement uncertainty.

  5. Detection limit - Wikipedia

    en.wikipedia.org/wiki/Detection_limit

    In analytical chemistry, the detection limit, lower limit of detection, also termed LOD for limit of detection or analytical sensitivity (not to be confused with statistical sensitivity), is the lowest quantity of a substance that can be distinguished from the absence of that substance (a blank value) with a stated confidence level (generally 99%).

  6. Pauling's rules - Wikipedia

    en.wikipedia.org/wiki/Pauling's_rules

    For typical ionic solids, the cations are smaller than the anions, and each cation is surrounded by coordinated anions which form a polyhedron.The sum of the ionic radii determines the cation-anion distance, while the cation-anion radius ratio + / (or /) determines the coordination number (C.N.) of the cation, as well as the shape of the coordinated polyhedron of anions.

  7. Chemical table file - Wikipedia

    en.wikipedia.org/wiki/Chemical_table_file

    A counts line is required, and must be first. It specifies the number of atoms, bonds, 3D objects, and Sgroups. It also specifies whether or not the CHIRAL flag is set. Optionally, the counts line can specify molregno. This is only used when the regno exceeds 999999 (the limit of the format in the molfile header line). The format of the counts ...

  8. Market order vs. limit order: How they differ and which type ...

    www.aol.com/finance/market-order-vs-limit-order...

    A limit order will not shift the market the way a market order might. The downsides to limit orders can be relatively modest: You may have to wait and wait for your price.

  9. Segregation (materials science) - Wikipedia

    en.wikipedia.org/wiki/Segregation_(Materials...

    In materials science, segregation is the enrichment of atoms, ions, or molecules at a microscopic region in a materials system. While the terms segregation and adsorption are essentially synonymous, in practice, segregation is often used to describe the partitioning of molecular constituents to defects from solid solutions, [1] whereas adsorption is generally used to describe such partitioning ...

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