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Vapour density is the density of a vapour in relation to that of hydrogen. It may be defined as mass of a certain volume of a substance divided by mass of same volume of hydrogen. vapour density = mass of n molecules of gas / mass of n molecules of hydrogen gas . vapour density = molar mass of gas / molar mass of H 2
Water vapor and dry air density calculations at 0 °C: The molar mass of water is 18.02 g/mol, as calculated from the sum of the atomic masses of its constituent atoms. The average molar mass of air (approx. 78% nitrogen, N 2; 21% oxygen, O 2; 1% other gases) is 28.57 g/mol at standard temperature and pressure .
This principle is included in the ideal gas equation: =, where n is the amount of substance. The vapour density (ρ) is given by =. Combining these two equations gives an expression for the molar mass in terms of the vapour density for conditions of known pressure and temperature:
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
where the pressure, p, is the atmospheric pressure, V is the measured volume of the vessel, T is the absolute temperature of the hot bath, and R is the gas constant. The molecular weight of the chemical is then simply the mass in grams of the vapor within the vessel divided by the calculated number of mole.
The saturation vapor density (SVD) is the maximum density of water vapor in air at a given temperature. [1] The concept is related to saturation vapor pressure (SVP). It can be used to calculate exact quantity of water vapor in the air from a relative humidity (RH = % local air humidity measured / local total air humidity possible ) Given an RH percentage, the density of water in the air is ...
The Antoine equation [3] [4] is a pragmatic mathematical expression of the relation between the vapor pressure and the temperature of pure liquid or solid substances. It is obtained by curve-fitting and is adapted to the fact that vapor pressure is usually increasing and concave as a function of temperature.
Relative density with respect to air can be obtained by =, where is the molar mass and the approximately equal sign is used because equality pertains only if 1 mol of the gas and 1 mol of air occupy the same volume at a given temperature and pressure, i.e., they are both ideal gases. Ideal behaviour is usually only seen at very low pressure.