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As of 2010s, the only commercial manufacturer of 1-pentene was Sasol Ltd., where it is separated from crude by the Fischer-Tropsch process. [2] 2-Pentene has two geometric isomers: cis-2-pentene and trans-2-pentene. Cis-2-Pentene is used in olefin metathesis.
The (E) isomer is classically obtained from the 3-chloropentanone by dehydrohalogenation. [6] It can also be obtained by dehydration of 4-hydroxy-pentan-2-one using oxalic acid as a catalyst. [5] 3-Penten-2-one occurs naturally in the berries of two species of Aronia melanocarpa. [7]
Pentane is an organic compound with the formula C 5 H 12 —that is, an alkane with five carbon atoms. The term may refer to any of three structural isomers, or to a mixture of them: in the IUPAC nomenclature, however, pentane means exclusively the n-pentane isomer, in which case pentanes refers to a mixture of them; the other two are called isopentane (methylbutane) and neopentane ...
These include meso compounds, cis–trans isomers, E-Z isomers, and non-enantiomeric optical isomers. Diastereomers seldom have the same physical properties. In the example shown below, the meso form of tartaric acid forms a diastereomeric pair with both levo- and dextro-tartaric acids, which form an enantiomeric pair.
Another example of this is the relationship between oleic acid and elaidic acid; oleic acid, the cis isomer, has a melting point of 13.4 °C, making it a liquid at room temperature, while the trans isomer, elaidic acid, has the much higher melting point of 43 °C, due to the straighter trans isomer being able to pack more tightly, and is solid ...
Methylene-interrupted polyenes are 1,4-pentadiene groups found in polyunsaturated fatty acids linoleic acid, α-linolenic acid, and arachidonic acid.These pentadiene derivatives are susceptible to lipid peroxidation, far moreso than monounsaturated or saturated fatty acids.
It is one of three structural isomers with the molecular formula C 5 H 12, the others being pentane (n-pentane) and neopentane (2,2-dimethylpropane). Isopentane is commonly used in conjunction with liquid nitrogen to achieve a liquid bath temperature of −160 °C.
For example, cyclobutane and methylcyclopropane are isomers of each other (C 4 H 8), but are not isomers of butane (C 4 H 10). Branched alkanes are more thermodynamically stable than their linear (or less branched) isomers. For example, the highly branched 2,2,3,3-tetramethylbutane is about 1.9 kcal/mol more stable than its linear isomer, n ...