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A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
2 consecutive measurements exceed 2 standard deviations of the reference range, and on the same side of the mean. Inaccuracy and/or imprecision R 4s: Two measurements in the same run have a 4 standard deviation difference (such as one exceeding 2 standard deviations above the mean, and another exceeding 2 standard deviations below the mean).
In statistics and in particular statistical theory, unbiased estimation of a standard deviation is the calculation from a statistical sample of an estimated value of the standard deviation (a measure of statistical dispersion) of a population of values, in such a way that the expected value of the calculation equals the true value.
σ g: Geometric standard deviation. This value is determined mathematically by the equation: σ g = D 84.13 /D 50 = D 50 /D 15.87. The value of σ g determines the slope of the least-squares regression curve. α: Relative standard deviation or degree of polydispersity. This value is also determined mathematically.
Its standard deviation is 32.9 and its average is 27.9, giving a coefficient of variation of 32.9 / 27.9 = 1.18; In these examples, we will take the values given as the entire population of values. The data set [100, 100, 100] has a population standard deviation of 0 and a coefficient of variation of 0 / 100 = 0
The "68–95–99.7 rule" is often used to quickly get a rough probability estimate of something, given its standard deviation, if the population is assumed to be normal. It is also used as a simple test for outliers if the population is assumed normal, and as a normality test if the population is potentially not normal.
The normal distribution is NOT assumed nor required in the calculation of control limits. Thus making the IndX/mR chart a very robust tool. Thus making the IndX/mR chart a very robust tool. This is demonstrated by Wheeler using real-world data [ 4 ] , [ 5 ] and for a number of highly non-normal probability distributions.
The mean and the standard deviation of a set of data are descriptive statistics usually reported together. In a certain sense, the standard deviation is a "natural" measure of statistical dispersion if the center of the data is measured about the mean. This is because the standard deviation from the mean is smaller than from any other point.