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Silver sulfate precipitates as a solid when an aqueous solution of silver nitrate is treated with sulfuric acid: . 2 AgNO 3 + H 2 SO 4 → Ag 2 SO 4 + 2 HNO 3. It is purified by recrystallization from concentrated sulfuric acid, a step that expels traces of nitrate. [7]
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/(100 mL)), unless shown otherwise. The substances are listed in alphabetical order.
In liquid water at high temperatures, (e.g. that approaching the critical temperature), the solubility of ionic solutes tends to decrease due to the change of properties and structure of liquid water; the lower dielectric constant results in a less polar solvent and in a change of hydration energy affecting the ΔG of the dissolution reaction.
Some silver oxide powder.. Silver is a relatively unreactive metal, although it can form several compounds. The common oxidation states of silver are (in order of commonness): +1 (the most stable state; for example, silver nitrate, AgNO 3); +2 (highly oxidising; for example, silver(II) fluoride, AgF 2); and even very rarely +3 (extreme oxidising; for example, potassium tetrafluoroargentate(III ...
When combined with silver, hydrogen sulfide gas creates a layer of black silver sulfide patina on the silver, protecting the inner silver from further conversion to silver sulfide. [8] Silver whiskers can form when silver sulfide forms on the surface of silver electrical contacts operating in an atmosphere rich in hydrogen sulfide and high ...
Silver sulfite can be prepared by dissolving silver nitrate with the stoichiometric quantity of sodium sulfite solution, yielding a precipitation of silver sulfite by the following reaction:
[1] [2] As water is an excellent solvent and is also naturally abundant, it is a ubiquitous solvent in chemistry. Since water is frequently used as the solvent in experiments, the word solution refers to an aqueous solution, unless the solvent is specified. [3] [4] A non-aqueous solution is a solution in which the solvent is a liquid, but is ...