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In thermodynamics, a critical point (or critical state) is the end point of a phase equilibrium curve. One example is the liquid–vapor critical point, the end point of the pressure–temperature curve that designates conditions under which a liquid and its vapor can coexist.
In quantum chemical calculations, the electron density, ρ(r), is a function of the coordinates r, defined so ρ(r)dr is the number of electrons in a small volume dr. For closed-shell molecules, ρ ( r ) {\displaystyle \rho (\mathbf {r} )} can be written in terms of a sum of products of basis functions, φ:
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
A sphere of radius r has surface area 4πr 2.. The surface area (symbol A) of a solid object is a measure of the total area that the surface of the object occupies. [1] The mathematical definition of surface area in the presence of curved surfaces is considerably more involved than the definition of arc length of one-dimensional curves, or of the surface area for polyhedra (i.e., objects with ...
Area density: ρ A: Mass per unit area kg⋅m −2: L −2 M: intensive Capacitance: C: Stored charge per unit electric potential farad (F = C/V) L −2 M −1 T 4 I 2: scalar Catalytic activity concentration: Change in reaction rate due to presence of a catalyst per unit volume of the system kat⋅m −3: L −3 T −1 N: intensive Chemical ...
A special type of area density is called column density (also columnar mass density or simply column density), denoted ρ A or σ.It is the mass of substance per unit area integrated along a path; [1] It is obtained integrating volumetric density over a column: [2] =.
The equivalence point, or stoichiometric point, of a chemical reaction is the point at which chemically equivalent quantities of reactants have been mixed. For an acid-base reaction the equivalence point is where the moles of acid and the moles of base would neutralize each other according to the chemical reaction.
The barn is also the unit of area used in nuclear quadrupole resonance and nuclear magnetic resonance to quantify the interaction of a nucleus with an electric field gradient. While the barn never was an SI unit, the SI standards body acknowledged it in the 8th SI Brochure (superseded in 2019) due to its use in particle physics .