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The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...
The molar volume of gases around STP and at atmospheric pressure can be calculated with an accuracy that is usually sufficient by using the ideal gas law. The molar volume of any ideal gas may be calculated at various standard reference conditions as shown below: V m = 8.3145 × 273.15 / 101.325 = 22.414 dm 3 /mol at 0 °C and 101.325 kPa
Until 1982, STP was defined as a temperature of 273.15 K (0 °C, 32 °F) and an absolute pressure of 101.325 kPa (1 atm). Since 1982, STP is defined as a temperature of 273.15 K (0 °C, 32 °F) and an absolute pressure of 100 kPa (1 bar). Conversions between each volume flow metric are calculated using the following formulas: Prior to 1982,
For a substance X with a specific volume of 0.657 cm 3 /g and a substance Y with a specific volume 0.374 cm 3 /g, the density of each substance can be found by taking the inverse of the specific volume; therefore, substance X has a density of 1.522 g/cm 3 and substance Y has a density of 2.673 g/cm 3. With this information, the specific ...
Note that the especially high molar values, as for paraffin, gasoline, water and ammonia, result from calculating specific heats in terms of moles of molecules. If specific heat is expressed per mole of atoms for these substances, none of the constant-volume values exceed, to any large extent, the theoretical Dulong–Petit limit of 25 J⋅mol ...
The van der Waals equation of state may be written as (+) =where is the absolute temperature, is the pressure, is the molar volume and is the universal gas constant.Note that = /, where is the volume, and = /, where is the number of moles, is the number of particles, and is the Avogadro constant.
When positive pressure is applied to a standard cubic foot of gas, it is compressed. When a vacuum is applied to a standard cubic foot of gas, it expands. The volume of gas after it is pressurized or rarefied is referred to as its "actual" volume. SCF and ACF for an ideal gas are related in accordance with the combined gas law: [2] [3]
Data obtained from Lange's Handbook of Chemistry, 10th ed. and CRC Handbook of Chemistry and Physics 44th ed. The annotation, d a°C/b°C, indicates density of solution at temperature a divided by density of pure water at temperature b known as specific gravity. When temperature b is 4 °C, density of water is 0.999972 g/mL.