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Propylamine, also known as n-propylamine, is an amine with the chemical formula CH 3 (CH 2) 2 NH 2. [1] It is a colorless volatile liquid. [2] Propylamine is a weak base. Its K b (base dissociation constant) is 4.7 × 10 −4.
Propanamide has the chemical formula CH 3 CH 2 C=O(NH 2). [1] It is the amide of propanoic acid. This organic compound is a mono-substituted amide. [2] Organic compounds of the amide group can react in many different organic processes to form other useful compounds for synthesis.
Pauling's second rule is that the value of the first pK a for acids of the formula XO m (OH) n depends primarily on the number of oxo groups m, and is approximately independent of the number of hydroxy groups n, and also of the central atom X. Approximate values of pK a are 8 for m = 0, 2 for m = 1, −3 for m = 2 and < −10 for m = 3. [28]
Hexylamine or n-hexylamine is a chemical compound with the formula CH 3 CH 2 CH 2 CH 2 CH 2 CH 2 NH 2. This colorless liquid is one of the isomeric amines of hexane. At standard temperature and pressure, it has the ammonia/bleach odor common to amines and is soluble in almost all organic solvents.
Like other simple aliphatic amines, ethylamine is a weak base: the pK a of [CH 3 CH 2 NH 3] + has been determined to be 10.8 [8] [9] Ethylamine undergoes the reactions anticipated for a primary alkyl amine, such as acylation and protonation. Reaction with sulfuryl chloride followed by oxidation of the sulfonamide give diethyldiazene, EtN=NEt. [10]
n-Butylamine is an organic compound (specifically, an amine) with the formula CH 3 (CH 2) 3 NH 2. This colourless liquid is one of the four isomeric amines of butane, the others being sec-butylamine, tert-butylamine, and isobutylamine. It is a liquid having the fishy, ammonia-like odor common to amines.
From the titration of protonatable group, one can read the so-called pK a 1 ⁄ 2 which is equal to the pH value where the group is half-protonated (i.e. when 50% such groups would be protonated). The pK a 1 ⁄ 2 is equal to the Henderson–Hasselbalch pK a (pK HH a) if the titration curve follows the Henderson–Hasselbalch equation. [14]
Isopropylamine can be obtained by reaction of isopropyl alcohol with ammonia in presence of a catalyst: [3] (CH 3) 2 CHOH + NH 3 → (CH 3) 2 CHNH 2 + H 2 O. Isopropylamine is a building block for the preparation of many herbicides and pesticides including atrazine, bentazon, glyphosate, imazapyr, ametryne, desmetryn, prometryn, pramitol, dipropetryn, propazine, fenamiphos, and iprodione. [3]