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The Henderson–Hasselbalch equation relates the pH of a solution containing a mixture of the two components to the acid dissociation constant, Ka of the acid, and the concentrations of the species in solution. [2] Simulated titration of an acidified solution of a weak acid (pKa = 4.7) with alkali. To derive the equation a number of simplifying ...
The pH of a solution is defined as the negative logarithm of the concentration of H+, and the pOH is defined as the negative logarithm of the concentration of OH-. For example, the pH of a 0.01M solution of hydrochloric acid (HCl) is equal to 2 (pH = −log 10 (0.01)), while the pOH of a 0.01M solution of sodium hydroxide (NaOH) is equal to 2 ...
The pH of a solution of a monoprotic weak acid can be expressed in terms of the extent of dissociation. After rearranging the expression defining the acid dissociation constant, and putting pH = −log 10 [H +], one obtains pH = pK a – log ( [AH]/[A −] ) This is a form of the Henderson-Hasselbalch equation. It can be deduced from this ...
where log denotes a logarithm to base 10 or common logarithm, and K diss is a stepwise acid dissociation constant. For bases, the base association constant , p K b is used. For any given acid or base the two constants are related by p K a + p K b = p K w , so p K a can always be used in calculations.
The partition coefficient, abbreviated P, is defined as a particular ratio of the concentrations of a solute between the two solvents (a biphase of liquid phases), specifically for un- ionized solutes, and the logarithm of the ratio is thus log P. [10]: 275ff When one of the solvents is water and the other is a non-polar solvent, then the log P ...
At half-neutralization the ratio [A −] / [HA] = 1; since log(1) = 0, the pH at half-neutralization is numerically equal to pK a. Conversely, when pH = pK a, the concentration of HA is equal to the concentration of A −. The buffer region extends over the approximate range pK a ± 2. Buffering is weak outside the range pK a ± 1.
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Equation used to calculate the pH of a weak acid or base solution. The Charlot equation, named after Gaston Charlot, is used in analytical chemistry to relate the hydrogen ion concentration, and therefore the pH, with the formal analytical concentration of an acid and its conjugate base. It can be used for computing the pH of buffer solutions ...